Time-dependent changes of arsenic and its selected forms in a hydroponic experiment with Quercus robur L.

Mutual transformations of particular As forms are dynamic. Therefore hydroponic experiments need to account for this variation. For this reason, the aim of the study was to determine the time-dependent changes of Astotal and selected forms of this metalloid (As(III), As(V), DMA or the sum of other organic forms) in modified Knop's solution and organs (root, low and high stem) of 2-year-old Quercus robur L. seedlings within a 33-day long hydroponic experiment. The results indicate the varying speed of As uptake and transport to aerial plant parts. A decrease in contents of As forms in organs of seedlings exposed to individual As forms varied, which indicates simultaneous transformations of As forms both in Knop's solution and plant organs. The obtained results indicate the need to analyse the main forms of As both in the nutrient solution and plant organs to assess the actual effectiveness of As phytoextraction by plants. It is necessary because, as demonstrated in this work, the addition of a specific As form does not mean that the capacity of a given plant relative to this form specifically is assessed. Capsule: The form of arsenic added to the medium undergoes dynamic changes affecting the phytoextraction of this metalloid in Quercus robur L. organs.