Literature DB >> 33072171

Photoprocessing of large PAH cations.

Gabi Wenzel1, Sarah Rodriguez Castillo1,2, Giacomo Mulas1,3, Ming-Chao Ji1, Anthony Bonnamy1, Hassan Sabbah1,4, Alexandre Giuliani5,6, Laurent Nahon5, Christine Joblin1.   

Abstract

In cosmic environments, polycyclic aromatic hydrocarbons (PAHs) strongly interact with vacuum ultraviolet (VUV) photons emitted by young stars. Trapped PAH cations ranging in size from 30 to 48 carbon atoms were irradiated by tunable synchrotron light (DESIRS beamline at SOLEIL). Their ionization and dissociation cross sections were determined and compared with TD-DFT computed photoabsorption cross sections. Evidence for radiative cooling is reported.

Entities:  

Keywords:  Astrochemistry; ISM: molecules; methods: laboratory; ultraviolet: ISM

Year:  2020        PMID: 33072171      PMCID: PMC7116201          DOI: 10.1017/S1743921319007063

Source DB:  PubMed          Journal:  Proc Int Astron Union        ISSN: 1743-9213


  2 in total

1.  VUV synchrotron radiation: a new activation technique for tandem mass spectrometry.

Authors:  Aleksandar R Milosavljević; Christophe Nicolas; Jean-Francois Gil; Francis Canon; Matthieu Réfrégiers; Laurent Nahon; Alexandre Giuliani
Journal:  J Synchrotron Radiat       Date:  2012-01-31       Impact factor: 2.616

2.  VUV photo-processing of PAH cations: quantitative study on the ionization versus fragmentation processes.

Authors:  Junfeng Zhen; Sarah Rodriguez Castillo; Christine Joblin; Giacomo Mulas; Hassan Sabbah; Alexandre Giuliani; Laurent Nahon; Serge Martin; Jean-Philippe Champeaux; Paul M Mayer
Journal:  Astrophys J       Date:  2016-05-10       Impact factor: 5.874

  2 in total

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