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Literature DB >> 33030477

On the reactivity of mRNA Cap0: C-H oxidative addition of 7-methylguanosine to Pt⁰ and base pairing studies.

Maria Inês P S Leitão¹, Carmen Gonzalez¹, Giulia Francescato¹, Zuzanna Filipiak¹, Ana Petronilho¹.

Abstract

7-Methylguanosine, whose lability to form an ylide/NHC has been known for decades, reacts with [Pt(PPh3)4] via C-H oxidative addition to yield a hydrido-PtII carbene complex. 1H NMR studies on Watson-Crick base-pairs showed no significant effect of metallation.

Entities: Chemical

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Year: 2020 PMID： 33030477 DOI： 10.1039/d0cc06075e

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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1 in total

1. Development of Triazoles and Triazolium Salts Based on AZT and Their Anti-Viral Activity against HIV-1.

Authors: Daniel Machado de Alencar; Juliana Gonçalves; Andreia Vieira; Sofia A Cerqueira; Cruz Sebastião; Maria Inês P S Leitão; Giulia Francescato; Paola Antenori; Helena Soares; Ana Petronilho
Journal: Molecules Date: 2021-11-06 Impact factor: 4.411

1 in total