| Literature DB >> 33006214 |
José M López-de-Luzuriaga1, Miguel Monge1, Sonia Moreno1, M Elena Olmos1, María Rodríguez-Castillo1.
Abstract
The assembly of two different building blocks, [{Au(C6 F5 )2 }{PbCl(terpy)}] (terpy=2,2':6':2''-terpyridine) and [{Au(C6 F5 )2 }2 {Pb(terpy)}]n , acting as terminal or central pieces, respectively, gives rise to a decanuclear complex built via metallophilic and π-stacking interactions in which the number of AuI ⋅⋅⋅AuI and AuI ⋅⋅⋅PbII contacts is finely controlled.Entities:
Keywords: computational studies; gold; lead; luminescence; metal-metal interactions
Year: 2020 PMID： 33006214 DOI： 10.1002/anie.202010095
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336