Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 A Stable Naked Dithiolene Radical Anion and Synergic THF Ring-Opening.

Literature DB >> 32985175

A Stable Naked Dithiolene Radical Anion and Synergic THF Ring-Opening.

Yuzhong Wang¹, Yaoming Xie¹, Pingrong Wei¹, Soshawn A Blair¹, Dongtao Cui¹, Michael K Johnson¹, Henry F Schaefer¹, Gregory H Robinson¹.

Abstract

Reaction of the lithium dithiolene radical 2• with the imidazolium salt [{(Me)CN(i-Pr)}2CH]+[Cl]- (in a 1:1 molar ratio) gives the first stable naked anionic dithiolene radical 3•, which, when coupled with hexasulfide, [{(Me)CN(i-Pr)}2CH]+2[S6]2- (4), and N-heterocyclic silylene 5, unexpectedly results in synergic THF ring-opening via a radical mechanism.

Entities: Chemical

Mesh：

Substances：

Year: 2020 PMID： 32985175 PMCID： PMC7682752 DOI： 10.1021/jacs.0c08495

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

32 in total

1. Pulsed ENDOR and ESEEM Study of [Bis(maleonitriledithiolato)nickel](-): An Investigation into the Ligand Electronic Structure.

Authors: Jennifer E. Huyett; Suranjan B. Choudhury; David M. Eichhorn; Peter A. Bryngelson; Michael J. Maroney; Brian M. Hoffman
Journal: Inorg Chem Date: 1998-03-23 Impact factor: 5.165

2. Synthesis and Reactivity of Organosamarium Diarylpnictide Complexes: Cleavage Reactions of Group 15 E-E and E-C Bonds by Samarium(II).

Authors: William J. Evans; John T. Leman; Joseph W. Ziller; Saeed I. Khan
Journal: Inorg Chem Date: 1996-07-17 Impact factor: 5.165

3. Electronic structure of neutral and monoanionic tris(benzene-1,2-dithiolato)metal complexes of molybdenum and tungsten.

Authors: Ruta R Kapre; Eberhard Bothe; Thomas Weyhermüller; Serena DeBeer George; Karl Wieghardt
Journal: Inorg Chem Date: 2007-06-14 Impact factor: 5.165

4. Covalent radii revisited.

Authors: Beatriz Cordero; Verónica Gómez; Ana E Platero-Prats; Marc Revés; Jorge Echeverría; Eduard Cremades; Flavia Barragán; Santiago Alvarez
Journal: Dalton Trans Date: 2008-04-07 Impact factor: 4.390

5. Correction: The role of polysulfide dianions and radical anions in the chemical, physical and biological sciences, including sulfur-based batteries.

Authors: Ralf Steudel; Tristram Chivers
Journal: Chem Soc Rev Date: 2019-07-29 Impact factor: 54.564

6. A silyl radical formed by muonium addition to a silylene.

Authors: Amitabha Mitra; Jean-Claude Brodovitch; Clemens Krempner; Paul W Percival; Pooja Vyas; Robert West
Journal: Angew Chem Int Ed Engl Date: 2010-03-12 Impact factor: 15.336

7. Sulfur K-edge X-ray absorption spectroscopy as a probe of ligand-metal bond covalency: metal vs ligand oxidation in copper and nickel dithiolene complexes.

Authors: Ritimukta Sarangi; Serena DeBeer George; Deanne Jackson Rudd; Robert K Szilagyi; Xavi Ribas; Concepció Rovira; Manuel Almeida; Keith O Hodgson; Britt Hedman; Edward I Solomon
Journal: J Am Chem Soc Date: 2007-02-02 Impact factor: 15.419

8. Beryllium derivatives of a phenyl-substituted β-diketiminate: a well-defined ring opening reaction of tetrahydrofuran.

Authors: Merle Arrowsmith; Mark R Crimmin; Michael S Hill; Gabriele Kociok-Köhn
Journal: Dalton Trans Date: 2013-05-17 Impact factor: 4.390

A Stable Naked Dithiolene Radical Anion and Synergic THF Ring-Opening.

1. Pulsed ENDOR and ESEEM Study of [Bis(maleonitriledithiolato)nickel](-): An Investigation into the Ligand Electronic Structure.

2. Synthesis and Reactivity of Organosamarium Diarylpnictide Complexes: Cleavage Reactions of Group 15 E-E and E-C Bonds by Samarium(II).

3. Electronic structure of neutral and monoanionic tris(benzene-1,2-dithiolato)metal complexes of molybdenum and tungsten.

4. Covalent radii revisited.

5. Correction: The role of polysulfide dianions and radical anions in the chemical, physical and biological sciences, including sulfur-based batteries.

6. A silyl radical formed by muonium addition to a silylene.

7. Sulfur K-edge X-ray absorption spectroscopy as a probe of ligand-metal bond covalency: metal vs ligand oxidation in copper and nickel dithiolene complexes.

8. Beryllium derivatives of a phenyl-substituted β-diketiminate: a well-defined ring opening reaction of tetrahydrofuran.

9. A single-component molecular metal based on a thiazole dithiolate gold complex.

10. N-Aryl substituted heterocyclic silylenes.

1. Mesoionic Dithiolates (MIDts) Derived from 1,3-Imidazole-Based Anionic Dicarbenes (ADCs).

2. A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion.

3. A Persistent Phosphanyl-Substituted Thioketyl Radical Anion.