Research on mechanism and characteristics of oil recovery from oily sludge in ultrasonic fields.

The acoustic parameters and operating conditions that determine efficiency of oil recovery from oily sludge are studied. Based on this, the mechanism of ultrasonic disintegration of oily sludge is analyzed. The results show that lower frequency ultrasound results in larger and more energetic cavitation bubbles that are more effective in the desorption of oil from solid particles. Moreover, acoustic intensity and treatment time that correspond to maximal oil recovery are found. Increasing the ratio of water to sludge and pH can reduce the slurry viscosity and facilitate the formation of HSiO3-, respectively, which improves the oil recovery efficiency. Moreover, Triton X-100 has better oil solubilizing effects than SDBS. After ultrasonic treatment, small amounts of asphaltenes are more stable on solid particles than other components. The heteroatoms such as S, N, and O in asphaltenes form hydrogen bonds with hydroxyl groups on the surface of the particles, impeding the desorption of oil. Mechanical effects such as shock waves and micro jets due to acoustic cavitation can break the hydrogen bonds between asphaltenes and solid particles, thereby facilitating oil recovery from oily sludge.