Highly Efficient Detection of Homologues and Isomers by the Dynamic Swelling Reflection Spectrum.

Precise and efficient detection of solvents with similar refractive index is highly desired but remains a big challenge for the conventional opal because the shift of its reflection wavelength only depends on the refractive index of the solvent to be detected. Here, homologues (alcohols, acids, alkalis, esters, and aromatic hydrocarbons), isomers, and other solvents with similar refractive index and structures were precisely distinguished through the dynamic swelling reflection spectrum (DSRS) pattern based on the different swelling behavior of swellable photonic paper in solvents. The one reflection signal of photonic paper will split into two reflection peaks, which then tend to merge together during the swelling process. The variation of the reflection signals and merging time are highly sensitive to the polarity and refractive index of the solvent, and the differences can be significantly amplified in DSRS, resulting in the distinction of the solvent from its unique geometric pattern. Moreover, the variation tendency of the reflectance provides an additional parameter in recognition of the solvent, which can be explained by calculation and comparison of the practical volume ratio of the solvent swelled into the photonic paper and the corresponding critical volume ratio of the solvent determined by its refractive index.