| Literature DB >> 32885573 |
Guojian Yang1,2, Yang Yu1,2, Baige Yang1,2, Tong Lu1,2, Yiru Cai2, Hang Yin3, Huiqi Zhang2, Ning-Ning Zhang1,2, Li Li2,4, Yu-Mo Zhang1,2, Sean Xiao-An Zhang1,2.
Abstract
A new and simple strategy towards electric-field-driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized base-responsive chiroptical polymer switch (R-FLMA) and p-benzoquinone (p-BQ) via proton-coupled electron transfer (PCET) mechanism. Clear and stable triple chirality states (silence, positive, negative) of this device in visible band can be regulated reversibly (>1000 cycles) by adjusting voltage programs. Furthermore, such chiral switching phenomena are also accompanied by apparent changes of color and fluorescence. More importantly, the potential application of this device for a spatial light modulator has also been demonstrated.Entities:
Keywords: chirality switching device; electrobase/acid; electrofluorochromism; proton-coupled electron transfer; spatial light modulators
Year: 2020 PMID： 32885573 DOI： 10.1002/anie.202009916
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336