Transition metal complexes incorporated with photoswitchable azo-based benzimidazole ligands: Photochromic and solvatochromic studies.

Photochromic compounds are well-known for their promising applications in many areas. It attracts remarkable attention because of their potential ability for optical memory media and optical switching devices. Herein, we have synthesized azo-based benzimidazole ligand and their transition metal complexes for photochromic applications in the liquid state. The azo-based benzimidazole ligand exhibits trans-to-cis photoisomerization with highly tunable and excellent π-π* and n-π* band separation of ligand, whereas complexes show light-induced photo-dissociation as well as trans-to-cis photoisomerization of the ligand part. The reverse cis-to-trans isomerization can be driven by without using light or any external stimuli at room temperature by keeping the system in the dark condition.