Core-shell structured cadmium sulfide nanocomposites for solar energy utilization.

Solar energy utilization technologies have been widely explored to solve the global energy crisis because the inexhaustible solar energy can be converted into chemical fuel and electricity. Various semiconductors that are crucial for solar energy utilization have been extensively developed. Among them, cadmium sulfide (CdS) has attracted extensive attention due to its suitable band-gap and excellent electrical/optical properties. However, CdS is still limited by rapid charge recombination, instability and low quantum efficiency. Core-shell structures can provide great opportunities for constructing advanced structures with superior properties to overcome the remaining challenges. This review focuses on the significant advances in core-shell structured CdS nanocomposites for solar energy utilization. Initially, the synthetic methods to construct core-shell structured CdS nanocomposites are reviewed. Then the applications in solar energy utilization are discussed, including photocatalytic\photoelectrochemical water splitting, photocatalytic CO2 reduction and solar cells. Finally, the perspectives of core-shell structured CdS nanocomposites for solar energy utilization are proposed.