Calibration Transfer for LED-Based Optical Multisensor Systems.

Multivariate calibration transfer is widely used to expand the applicability of the existing regression model to new analytical devices of the same or similar type. The present research proves the feasibility of calibration model transfer between a full-scale laboratory spectrometer and an optical multisensor system based on only four light-emitting diodes with different wavelengths. The model transfer between two multisensor systems of this kind has also been studied. Both possibilities were successfully performed without any significant loss of precision using a designed set of training and transfer samples. Direct standardization and slope and bias correction protocols for model transfer were tested and compared. The best model transfer between two optical multisensor systems was obtained using direct standardization.