Literature DB >> 32633282

An unsymmetrical binuclear iminopyridine-iron complex and its catalytic isoprene polymerization.

Liang Wang1, Xiaowu Wang1, Hongbin Hou1, Guangqian Zhu2, Zhenyu Han2, Weiying Yang2, Xiao Chen1, Qinggang Wang1.   

Abstract

A series of chloride-bridged unsymmetrical mixed Fe(ii)-HS/Fe(ii)-LS binuclear structures has been prepared and characterized. Upon activation with MAO, highly efficient catalytic polymerization of isoprene was achieved, delivering an ultra-high molecular weight (catalyst loading = 2.5 ppm, Mn = 1.8 × 106 g mol-1, Mw/Mn = 1.4).

Entities:  

Year:  2020        PMID: 32633282     DOI: 10.1039/d0cc04122j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Synthesis, Characterization and Catalytic Property Studies for Isoprene Polymerization of Iron Complexes Bearing Unionized Pyridine-Oxime Ligands.

Authors:  Mengmeng Zhao; Ying Ma; Xianhui Zhang; Liang Wang; Guangqian Zhu; Qinggang Wang
Journal:  Polymers (Basel)       Date:  2022-09-01       Impact factor: 4.967

  1 in total

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