Impact of human activities on coastal groundwater pollution in the Yang-Dai River plain, northern China.

Overexploitation of groundwater has resulted in seawater intrusion in many semiarid and arid coastal areas. This study illustrates the origin of groundwater salinity and assesses seawater intrusion/extrusion process in the Yang-Dai River plain aquifer, by analyzing hydrochemical and stable isotopic compositions of surface water, groundwater, geothermal water, and seawater. A cone of depression in groundwater is caused by intensive groundwater pumping formed in the late 1980s in the alluvial Yang-Dai River plain. In the northern part, groundwater exploitation has caused seawater intrusion identified by Ca-Cl type water. However, the widely distributed silty clay prevented the seawater intrusion in the southern part, evidenced by Ca-HCO3 type water with depleted δ2H (-60 to -46‰) and δ18O (-8.9 to -4.7‰). Anthropogenic pollution also plays a significant role in groundwater salinization. The positive correlation between Cl and NO3- for most groundwater and the extremely high nitrate concentrations (up to 652.7 mg/L) indicate that fertilizer from agricultural activities has greatly influenced groundwater quality. Irrigation return flow evaporation during agricultural activities also accounts for groundwater salinity. Besides the intensive fertilizer usage, seawater intrusion and the established anti-tide dams reduced the surface water and groundwater discharge to the sea and then resulted in the extremely high nitrate concentration. This study may improve the understanding of the groundwater salinization processes in a complex coastal aquifer, which is greatly influenced by anthropogenic activities.