Literature DB >> 32601512

The Reaction of β,γ-Epoxy Alcohols with Titanium(III) Reagents. A Proposed Role for Intramolecular Hydrogen Bonding.

Sven Klare1, Jonathan P Gordon2, Andreas Gansäuer1, T V RajanBabu2, William A Nugent2.   

Abstract

Entities:  

Keywords:  Epoxides; Free radicals; Hydrogen bonding; Mechanism; Titanium(III)

Year:  2019        PMID： 32601512      PMCID： PMC7322769          DOI： 10.1016/j.tet.2019.130662

Source DB:  PubMed          Journal:  Tetrahedron        ISSN： 0040-4020            Impact factor:   2.457


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  31 in total

1.  Cp2TiCl-mediated selective reduction of alpha,beta-epoxy ketones.

Authors:  C Hardouin; F Chevallier; B Rousseau; E Doris
Journal:  J Org Chem       Date:  2001-02-09       Impact factor: 4.354

2.  Reagent-controlled transition-metal-catalyzed radical reactions.

Authors:  A Gansäuer; H Bluhm
Journal:  Chem Rev       Date:  2000-08-09       Impact factor: 60.622

3.  H2O activation for hydrogen-atom transfer: correct structures and revised mechanisms.

Authors:  Andreas Gansäuer; Maike Behlendorf; Asli Cangönül; Christian Kube; Juan M Cuerva; Joachim Friedrich; Maurice van Gastel
Journal:  Angew Chem Int Ed Engl       Date:  2012-02-15       Impact factor: 15.336

4.  Asymmetric synthesis of the cytotoxic marine natural product (+)-awajanomycin and its C-11 epimer.

Authors:  Rui Fu; Jian-Liang Ye; Xi-Jie Dai; Yuan-Ping Ruan; Pei-Qiang Huang
Journal:  J Org Chem       Date:  2010-06-18       Impact factor: 4.354

5.  Bond-weakening catalysis: conjugate aminations enabled by the soft homolysis of strong N-H bonds.

Authors:  Kyle T Tarantino; David C Miller; Ted A Callon; Robert R Knowles
Journal:  J Am Chem Soc       Date:  2015-05-13       Impact factor: 15.419

6.  Synthetic and computational evaluation of regiodivergent epoxide opening for diol and polyol synthesis.

Authors:  Andreas Gansäuer; Peter Karbaum; David Schmauch; Martin Einig; Lili Shi; Anakuthil Anoop; Frank Neese
Journal:  Chem Asian J       Date:  2014-04-29

7.  Mechanism of titanocene-mediated epoxide opening through homolytic substitution.

Authors:  Andreas Gansäuer; Andriy Barchuk; Florian Keller; Martin Schmitt; Stefan Grimme; Mareike Gerenkamp; Christian Mück-Lichtenfeld; Kim Daasbjerg; Heidi Svith
Journal:  J Am Chem Soc       Date:  2007-02-07       Impact factor: 15.419

8.  Mechanistic study of the titanocene(III)-catalyzed radical arylation of epoxides.

Authors:  Andreas Gansäuer; Daniel von Laufenberg; Christian Kube; Tobias Dahmen; Antonius Michelmann; Maike Behlendorf; Rebecca Sure; Meriam Seddiqzai; Stefan Grimme; Dhandapani V Sadasivam; Godfred D Fianu; Robert A Flowers
Journal:  Chemistry       Date:  2014-10-28       Impact factor: 5.236

9.  Regio- and diastereoselective reductive coupling of vinylepoxides catalyzed by titanocene chloride.

Authors:  Alejandro F Barrero; José F Quílez del Moral; Elena M Sánchez; Jesús F Arteaga
Journal:  Org Lett       Date:  2006-02-16       Impact factor: 6.005

10.  Rhodium-catalyzed asymmetric hydrogenation of β-cyanocinnamic esters with the assistance of a single hydrogen bond in a precise position.

Authors:  Xiuxiu Li; Cai You; Yusheng Yang; Yuhong Yang; Pan Li; Guoxian Gu; Lung Wa Chung; Hui Lv; Xumu Zhang
Journal:  Chem Sci       Date:  2018-01-04       Impact factor: 9.825
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