A reaction-based sensing scheme for volatile organic amine reagents with the chromophoric-fluorogenic dual mode.

In this study, we present the classical Michael's addition reaction-based sensing scheme for volatile organic amine reagents such as ethylenediamine, N, N-dimethylethylenediamine and diethylenetriamine using a near-infrared fluorescent dye TCF1. Obvious spectral changes in the UV-vis absorption and fluorescence spectra of TCF1 were observed upon addition of these amine reagents with an effective catalyst DBU, resulting in significant and fast color changes detectable by the naked-eye. TCF1 showed an efficient response to these amine reagents with a low detection limit, especially for diethylenetriamine. NMR and MS spectral analysis proved that the mechanism of the detection was based on the classical Michael addition, which was also verified by the theoretical calculations. In addition, a portable test paper incorporated with TCF1 had also successfully realized the detection of a low concentration of these amine reagents.