Literature DB >> 32579654

Asymmetric [N-I-N]+ halonium complexes.

Jas S Ward1, Giorgia Fiorini1, Antonio Frontera2, Kari Rissanen1.   

Abstract

The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6 (2c) and [I(py)(4-Etpy)]PF6 (2e) were prepared via [N-Ag-N]+ → [N-I-N]+ cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by 1H and 1H-15N HMBC NMR spectroscopy, and single crystal X-ray crystallography.

Entities:  

Year:  2020        PMID: 32579654     DOI: 10.1039/d0cc02758h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Hydrogen Bond and Other Lewis Acid-Lewis Base Interactions as Preliminary Stages of Chemical Reactions.

Authors:  Sławomir J Grabowski
Journal:  Molecules       Date:  2020-10-13       Impact factor: 4.411

2.  Halogen Bond of Halonium Ions: Benchmarking DFT Methods for the Description of NMR Chemical Shifts.

Authors:  Daniel Sethio; Gerardo Raggi; Roland Lindh; Máté Erdélyi
Journal:  J Chem Theory Comput       Date:  2020-11-02       Impact factor: 6.006

3.  Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines.

Authors:  Jas S Ward; Rosa M Gomila; Antonio Frontera; Kari Rissanen
Journal:  RSC Adv       Date:  2022-03-21       Impact factor: 3.361

  3 in total

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