Literature DB >> 32555889

Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis.

Yuto Shimoyama1, Zhewei Weng1, Naoki Ogiwara1, Takashi Kitao2, Yuji Kikukawa3, Sayaka Uchida1.   

Abstract

Eleven isostructural mesoporous ionic crystals (meso-PICs) are synthesized. The initial activities of the Barbier-Grignard reaction, which is a typical C-C bond formation reaction, catalyzed by the meso-PICs are dependent on the acid dissociation constant of the aqua ions of Mn+ and the types of polyoxometalates, which construct the meso-PICs.

Entities:  

Year:  2020        PMID： 32555889     DOI： 10.1039/d0dt01202e

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  1 in total

1.  Polyoxocationic antimony oxide cluster with acidic protons.

Authors:  Yuki Watanabe; Kim Hyeon-Deuk; Takafumi Yamamoto; Masayoshi Yabuuchi; Olesia M Karakulina; Yasuto Noda; Takuya Kurihara; I-Ya Chang; Masanobu Higashi; Osamu Tomita; Cédric Tassel; Daichi Kato; Jingxin Xia; Tatsuhiko Goto; Craig M Brown; Yuto Shimoyama; Naoki Ogiwara; Joke Hadermann; Artem M Abakumov; Sayaka Uchida; Ryu Abe; Hiroshi Kageyama
Journal:  Sci Adv       Date:  2022-06-17       Impact factor: 14.957
  1 in total

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