Literature DB >> 32519684

Improved photocatalytic performance of metal-organic frameworks for CO2 conversion by ligand modification.

Xiuyan Cheng1, Jianling Zhang2, Xiuniang Tan1, Lirong Zheng3, Dongxing Tan1, Lifei Liu1, Gang Chen1, Qiang Wan1, Bingxing Zhang1, Fanyu Zhang1, Zhuizhui Su1, Buxing Han2, Jing Zhang3.   

Abstract

Here we demonstrate that the utilization of 2,4,6-tris(4-pyridyl)pyridine (tpy) for metal-organic framework modification can greatly improve the photocatalytic performance for CO2 reduction. The electron-donating nature of tpy enables the charge transfer effect, which induces strong CO2 binding affinity, facilitates *COOH formation and promotes CO2-to-CO conversion.

Entities:  

Year:  2020        PMID: 32519684     DOI: 10.1039/d0cc02707c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  High selective photocatalytic CO2 conversion into liquid solar fuel over a cobalt porphyrin-based metal-organic framework.

Authors:  N Sadeghi; Mika Sillanpää
Journal:  Photochem Photobiol Sci       Date:  2021-03-12       Impact factor: 3.982

2.  Controlled synthesis of Bi- and tri-nuclear Cu-oxo nanoclusters on metal-organic frameworks and the structure-reactivity correlations.

Authors:  Qi Xue; Bryan Kit Yue Ng; Ho Wing Man; Tai-Sing Wu; Yun-Liang Soo; Molly Mengjung Li; Shogo Kawaguchi; Kwok Yin Wong; Shik Chi Edman Tsang; Bolong Huang; Tsz Woon Benedict Lo
Journal:  Chem Sci       Date:  2021-11-29       Impact factor: 9.825

  2 in total

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