Literature DB >> 32507212

MPEG grafted alkylated carboxymethyl chitosan as a high-efficiency demulsifier for O/W crude oil emulsions.

Renliang Lyu1, Ting Xia1, Cheng Liang1, Cheng Zhang1, Zeqin Li1, Lichun Wang2, Yi Wang1, Ming Wu3, Xiaogang Luo4, Jiayu Ma1, Cunwen Wang1, Caili Xu5.   

Abstract

Three kinds of novel environmentally benign and high-efficiency crude oil demulsifiers were prepared using methoxy polyethylene glycol (MPEG) to modify alkylated carboxymethyl chitosan (ACMC). Structures of the demulsifiers were confirmed using FT-IR and 1H NMR, and the relationship between surface tension and concentration was tested. Demulsification performance was investigated using the bottle test method with oil-in-water (O/W) emulsions that were prepared in lab conditions. The demulsification efficiency was as high as 79.1 %-84.9 %, and the possible mechanism of the demulsification process is discussed. Results show that MPEG-grafted ACMC (MPEG-ACMC) has a promising application as a demulsifier for dealing with emulsified O/W crude oil.
Copyright © 2020 Elsevier Ltd. All rights reserved.

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Keywords:  (ACMC); (MPEG); 1-bromobutane (Pubchem CID: 8002); 1-bromohexane (Pubchem CID: 8101); 1-bromooctane (Pubchem CID: 8140); Alkylated; Carboxymethyl chitosan; Chitosan (Pubchem CID: 129662530); Demulsification efficiency; Methoxy polyethylene glycol; Surface tension; acetone (Pubchem CID: 180); isopropanol (Pubchem CID: 3776); potassium hydroxide (Pubchem CID: 14797); sodium chloroacetate (Pubchem CID: 23665759); succinic anhydride (Pubchem CID: 7922); triethylamine (Pubchem CID: 8471)

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Year:  2020        PMID: 32507212     DOI: 10.1016/j.carbpol.2020.116309

Source DB:  PubMed          Journal:  Carbohydr Polym        ISSN: 0144-8617            Impact factor:   9.381


  3 in total

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2.  Synthesis of Hydroxypropyltrimethyl Ammonium Chitosan Derivatives Bearing Thioctate and the Potential for Antioxidant Application.

Authors:  Wenqiang Tan; Conghao Lin; Jingjing Zhang; Qing Li; Zhanyong Guo
Journal:  Molecules       Date:  2022-04-21       Impact factor: 4.927

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  3 in total

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