Preparation of lignin containing cellulose nanofibers and its application in PVA nanocomposite films.

Lignin containing cellulose nanofibers (LCNFs) were successfully prepared from wheat straw using an acid hydrotrope of p-toluene sulfonic acid (p-TsOH) combined with ultrasonication. p-TsOH pretreatment was applied below 80 °C to selectively remove hemicellulose and lignin and generate purified cellulose fibers containing approximately 15% lignin. Subsequently, high-intensity ultrasonication was used for <6 min to effectively defibrillate the p-TsOH-pretreated cellulose fibers to nanoscale fibers. AFM and TEM analyses showed that the diameter distribution of the resultant nanofibers decreased with the increase in ultrasonic intensity. The FTIR and XRD results indicated that the molecular structures and cellulose crystallinity were not changed during the ultrasonic process. An amount of 5 wt% of the obtained LCNFs was introduced into a polyvinyl alcohol (PVA) matrix. The resulting nanocomposite products exhibited improved thermal performance and surface properties compared with the pure PVA matrix. The mechanical properties, including the tensile stress and Young's modulus, were enhanced significantly, although the elongation at the break was slightly decreased. PVA composites with the addition of LCNFs are expected to be used in a variety of fields, such as biodegradable plastics, pharmaceutical carrier, filtration media and packaging materials.