Literature DB >> 32427246

Dipyridinoarsole: a new class of stable and modifiable heteroatom-bridged bipyridines.

Toshiki Fujii1, Susumu Tanaka, Shotaro Hayashi, Hiroaki Imoto, Kensuke Naka.   

Abstract

Herein, we report our experimental and computational investigations on a stable and modifiable As-bridged dipyridinoheterole, dipyridinoarsole. Oxidation of the arsenic atom changes the frontier orbital energies and quaternization of nitrogen atoms produces electrochromic materials. Dipyridinoarsole is suitable for practical applications due to its superior stability compared to its phosphole analogues.

Entities:  

Year:  2020        PMID: 32427246     DOI: 10.1039/d0cc02389b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Synthesis, Structural Characterization, and Optical Properties of Benzene-Fused Tetracyclic and Pentacyclic Stiboles.

Authors:  Mio Matsumura; Yuki Matsuhashi; Masato Kawakubo; Tadashi Hyodo; Yuki Murata; Masatoshi Kawahata; Kentaro Yamaguchi; Shuji Yasuike
Journal:  Molecules       Date:  2021-01-04       Impact factor: 4.411

2.  Phosphoryl- and phosphonium-bridged viologens as stable two- and three-electron acceptors for organic electrodes.

Authors:  Colin R Bridges; Andryj M Borys; Vanessa A Béland; Joshua R Gaffen; Thomas Baumgartner
Journal:  Chem Sci       Date:  2020-09-21       Impact factor: 9.825

  2 in total

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