Heavy metal concentrations in urban snow as an indicator of air pollution.

Manganese, Zn, Pb, Cu, Cr and Cd concentrations in snow collected in and around urban areas and from snow dumping stations in Hokkaido were determined by Zeeman-type atomic absorption spectrophotometry. We compared the heavy metal concentrations in the snow with background levels to see whether they could be used as an effective indicator of urban air pollution. The heavy metal concentrations in the snow clearly increased towards the center of the city of Sapporo; they were influenced by local pollution in the industrial area of the city and by the effect of the seasonal wind from the northwest. In the cities, we found the greatest influence on heavy metal concentrations was air pollution caused by industrial activities. The elemental concentrations in urban snow were from several to tens of times higher than background levels. The mean concentrations of the elements studied were in the order Mn greater than Zn greater than Pb greater than Cu greater than Cr greater than Cd, the same as in water except for Pb. We propose that data on trace metal concentrations in snow are a reliable guide to the degree of air pollution, and can be used as a simple and effective indicator of urban air pollution.