Literature DB >> 32384732

Directed Polymers and Interfaces in Disordered Media.

Róbinson J Acosta Diaz1, Christian D Rodríguez-Camargo2,3, Nami F Svaiter4.   

Abstract

We consider field theory formulation for directed polymers and interfaces in the presence of quenched disorder. We write a series representation for the averaged free energy, where all the integer moments of the partition function of the model contribute. The structure of field space is analysed for polymers and interfaces at finite temperature using the saddle-point equations derived from each integer moments of the partition function. For the case of an interface we obtain the wandering exponent ξ = ( 4 - d ) / 2 , also obtained by the conventional replica method for the replica symmetric scenario.

Entities:  

Keywords:  disordered systems; free energy; wandering exponent

Year:  2020        PMID: 32384732      PMCID: PMC7284553          DOI: 10.3390/polym12051066

Source DB:  PubMed          Journal:  Polymers (Basel)        ISSN: 2073-4360            Impact factor:   4.329


1. Introduction

The statistical mechanics of random surfaces and membranes, or more generally of extended objects, has been widely discussed in the literature, see, e.g., [1]. One of the simplest example of a tethered surfaces are the polymers [2,3,4]. Certain models of polymers can be discussed by a classical field theory [5,6,7]. Directed polymers in the presence of a quenched random potential describe, for example, the behavior of a linear elastic objects with no self-intersections in a porous medium and also the polymer behavior in poor solvents [8,9]. The generalization to more complex extended objects is straightforward [10,11,12,13,14,15]. One can also consider a d-dimensional manifold with internal points , embedded in an external D-dimensional space with position vector , where . For oriented manifolds, the set of N transverse coordinates describe the fields of the model. The case describes an interface in a quenched random potential. In these systems with disorder, two averages must be performed. The average of a thermal ensemble using the Boltzmann weight and also the average over all the realizations of the disordered variables. For quenched disorder, one is mainly interested in averaging the free energy over the disorder, which amounts to averaging the logarithm of the partition function. In the field theory of random manifolds, a technique that has been used in order to compute the average free energy is the replica method [16,17,18,19,20,21]. It is known that there are criticisms concerning the fundamental mathematics behind such method [22,23,24,25,26,27]. Nevertheless this procedure has succeed in describing polymers and membranes in a random media. A nice discussion about the limit can be found in Ref. [28,29] The main mathematical problem of the replica trick is that it is not possible to interpret the above discussed limit as an analytical continuation procedure. The aim of this paper is to present an alternative to the replica trick. We study directed polymers and fluctuating interfaces in quenched random potentials, where we compute the wandering exponent in a generic d-dimensional manifold. We obtain that the wandering exponent is given by as was discussed in Ref. [30], for the replica symmetric structure of the correlation functions. A new method to calculate the average free energy of systems defined in the continuum with quenched disorder was presented in Refs. [31,32]. An application of such procedure was presented in Ref. [33,34] where a Landau-Ginzburg model with a disorder field linearly and quadratically coupled with the order parameter was discussed. The static version of a non-relativistic field theory with a complex field was investigated in [35]. There, an interacting boson system below the critical condensation temperature was studied. It was discussed the effects of quenched disorder in a dilute Bose- Einstein condensate confined in a hard walls trap. Using the disordered Gross-Pitaevskii functional, a representation for the quenched free energy as a series of integer moments of the partition function was obtained, where positive and negative disorder-dependent effective coupling constants appear in the integer moments. The combined contributions of effects due to boundary conditions and disorder in the weakly disordered condensate was analysed, and the ground state renormalized density profile of the condensate was presented. This new technique was also used to discuss fluctuations of the Hawking temperature in an Euclidean Schwarzschild manifold [36]. The organization of this paper is as follows. In Section 2, we discuss directed polymers in the presence of a quenched disorder. In Section 3, the average free energy associated with a manifold in the presence of a quenched disorder is presented. Conclusions are given in Section 4. We use .

2. The Field Theory in with Quenched Disorder

Let us consider a directed polymer of length L, where for simplicity we assume that the displacements of the polymer can occur in one direction. In the continuum approximation, the Hamiltonian of the directed polymer can be written as where c is the linear tension of the polymer, x is the longitudinal coordinate , and is the transverse displacement of the polymer with respect to the straight line. Finally, is the quenched disordered potential of the model [37,38,39,40,41,42]. There are different proposed probability distributions associated with the disorder. A widely used probability distribution is the Gaussian (normal) distribution. We will take to be a Gaussian random variable which has zero mean and it is delta-correlated in the transverse direction. Therefore and where means the average over all realizations of the quenched random potential and stands for the correlation function of the model. The scaling relation defines the wandering exponent. We have where is a thermal average, i.e., the configurational average of the Boltzmann weight. The quantity is the polymer mean squared displacement with length L where is the wandering exponent. The partition function of the model can be written as where is a formal functional measure. The average free energy is defined as where is the probability distribution associated with the disorder. To obtain the average free energy of the model we can use the replica method. For an application of this method to study finite size effects in the random field Ising model see the Ref. [43]. Inspired in the usual situation where one defines zeta functions in terms of countable collections of numbers [44,45,46,47] and also defining the zero point energy of quantum fields in the presence of boundaries [48,49,50], we define the distributional zeta function as for , this function being defined in open connected subset of the complex plane. The average free energy can be computed using Next, one can write using the Euler integral representation for the Gamma function. Breaking this integral representation into two integrals, one from zero to a and another from a to infinity, where a is an arbitrary real number, and expanding the exponential in power series in the first integral, one can write that the average free energy is [31,32] where is the Euler-Mascheroni constant and For large a it is possible to work only with the series contributions. Next, we absorb the dimensionless parameter a in the functional integral measure. To proceed, let be the k-th power of the partition function, for k integer. In this case, we have a perturbative expansion of the average free energy given by Equation (9). The k-th power of the partition function can be written as Averaging over the disorder we obtain that the k-th moment of the partition function is given by where the effective Hamiltonian is We would like to stress that the method used in this paper, contrary to the replica method neither involves derivatives of the integer moments of the partition function, nor the extension to this derivative to non-integer values of k. Now, we have to discuss the quantity defined in Equation (3). It is well know that the delta correlated potential maps the replicated problem to interacting quantum bosons.Using that is given by permits an entire analysis via replicas [42]. Since we are interested in a soluble model, we assume that is given by Equation (14). After integrating by parts, we can write that , where and Studying the replica field theory for the problem of fluctuating manifold in a quenched random potential, Mézard and Parisi and others introduced a mass term in the effective Hamiltonian in order to regularize the model [30,51]. Indeed, in the high temperature limit, i.e., the operator has the zero eigenvalue and therefore is not invertible. To circumvent this problem, we are following the same idea introducing the term in the effective Hamiltonian . Neglecting , we have In the limit where we recover the polymer field theory. To find the contribution to the k-th term, of the series that defines the quenched free energy, let us define the operator in field space. We have Within this definition, we can write as Therefore, reads Substituting the above equation into Equation (9) we obtain the average free energy of the system. A point that deserves be emphasized is the fact that the number of terms in the series that represents the average free energy can be finite. For instance, we can use the saddle-point equation to find a bound for k. Therefore, let us discus the saddle-point equations of the model. For each moment of the partition function, the saddle-point equations are In each integer moment of the partition function, we must have . This is the unique solution for the problem of the structure in field space in each moment of the partition function. For equal fields, the saddle-point equation becomes The condition must be satisfied to have a physical theory. Consider a generic term of the series given by Equation (9) with a moment of the partition function given by . Defining as where means the integer part of x, the structure of the fields in each moment of the partition function is given by Only in the high-temperature limit, , all the moments of the partition functions contribute to the average free energy. For finite temperature, we must have only a finite number of terms in the series representation to the average free energy. In this case, using Equation (24) the average free energy is given by For and large we have the large-N approximation for a Gaussian field theory. It is interesting to point out that the limit , we must have . The system is described by a field theory where the dimension of the order parameter is one. In the next section, we discuss another Gaussian model defined in the continuous limit and calculate its wandering exponent.

3. Field Theory for Interfaces in Random Media

In this section, we study an interface. We consider a d-dimensional manifold with internal points, , embedded in an external D-dimensional space with position vector . We are considering a d-dimensional manifold in a dimensional space. For oriented manifolds, we can describe the system in terms of the set of transverse coordinates, where N is the number of transverse dimensions. We are interested in the case , so we have an interface in a quenched random potential and . The Hamiltonian of the domain wall can be written as where is the domain wall stiffness and is the quenched random potential of the model [14,15]. Following Mezard and Parisi and also Cugliandolo et al. [30,51], let us introduce a contribution, which constrain the manifold to fluctuate in a restricted volume of the embedding space. The regularized Hamiltonian becomes The partition function of the model is given by where is a functional measure. We are assuming that the probability distribution associated to the random potential has zero mean and correlator where again, the means that we are taking the average over all the realizations of the quenched random potential. Since we are assuming that the system has a quenched random potential, the average free energy is defined as With Equation (9) in hands, we have to compute k-th moment of the partition function, . After integrating over the disorder, we get where Again, as in the case of the polymers, to proceed we must use some model for . Following Balents and Fisher [52], we consider that can be written as Now, let us discuss the model going beyond the Gaussian approximation. Assuming that that , and for . The potential reads In this case, the k-th moment of the partition function is given by where the effective Hamiltonian can be written as In the above equation, the Gaussian contribution is given by and the non-Gaussian contribution is We are interested in studying the structure of the field space. Using the saddle-point equations and assuming the symmetry ansatz, for all fields in each moment of the partition function, we have that the saddle-point equation reads The condition must be satisfied to have a physical theory. Let us define and considering again a generic term of the series, given by Equation (9), with the moment of the partition function, , the only choice in the field space is given by the average free energy becomes where is given by Equation (35) and the effective Hamiltonian, by Equations (36)–(38). With the choice of the field space we obtain that the effective Hamiltonian can be written in the simple form where for simplicity we are using and reads Therefore, in Equation (41), the quantity is given by In the symmetric ansatz framework, all the series that represents the average free energy can be viewed as an Euclidean field theory for a k-component scalar field. Defining the k-vector field with the components , we can write the effective Hamiltonian as where stands for the transpose of the k-vector . In view of Equations (43) and (44), the kernel is where is the k-dimensional identity matrix and is the square k-dimensional matrix with all elements 1 [53]. Our aim now is to study the two-point correlation function of the Euclidean field theory for a k- component scalar field. Performing a Fourier transform we get where is the inverse of the two-point correlation function, Using the projectors operators we can write the two-point correlation function as The first term in the right hand side of Equation (48) is the bare contribution to the connected two-point correlation function; the second term is the contribution to the disconnected two-point correlation function, which becomes connected after averaging the disorder. Let us study the two-point correlation function. First write with and where Now we are able to discuss the functional form of and . A straightforward computation yields Also we can write that In the case which we are interested in, one must take the limit of , since , only the contribution from survives. From Equations (52) and (53) we have We can introduce a normalized generating functional with the normalization factor where the prime sign means that the contribution of the zero mode must be omitted. The wandering exponent describes the growth of the transverse fluctuations of the manifold as function of the distances. In the limit , we obtain from Equation (48) the wandering exponent given by as was discussed by Parisi and Mézard in Ref. [30], discussing the replica symmetric solution.

4. Conclusions

For quenched disorder, we are mainly interested in averaging the free energy over the disorder, which amounts to averaging the logarithm of the partition function. The standard replica method is a powerful tool used to calculate the free energy of systems with quenched disorder. In this paper, we computed the average free energy of directed polymer and a fluctuating interface in the presence of a quenched disorder. To find the average free energy for both systems, we define a distributional zeta-function. The derivative of this function at the origin yields the average free energy of the underlying system. The average free energy of a system with quenched disorder is represented by a series in which all the moments of the partition functions contribute. In the case of a polymer and an interface in a quenched random potential, we were able to discuss the field theory generated by each term of the series that defines the average free energy. Each term of the series that represents the average free energy is an Euclidean field theory for a k-component scalar field. As an application of the distributional zeta-function method, we calculate the wandering exponent in a generic d-dimensional manifold. We obtain that the wandering exponent given by . This result was discussed by Parisi and Mézard in Ref. [30] in the replica symmetry scenario.
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10.  Directed polymers and interfaces in random media: free-energy optimization via confinement in a wandering tube.

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