Literature DB >> 32369052

A convenient reagent for the conversion of aldoximes into nitriles and isonitriles.

Wei Zhang1, Jin-Hong Lin, Pengfei Zhang, Ji-Chang Xiao.   

Abstract

For the dehydroxylation of aldoximes with 4-nitro-1-((trifluoromethyl)sulfonyl)-imidazole (NTSI), slight modifications of reaction conditions resulted in significantly different reaction paths to provide either nitriles or isonitriles. The challenging conversion of aldoximes into isonitriles was achieved under mild conditions.

Entities:  

Year:  2020        PMID: 32369052     DOI: 10.1039/d0cc00188k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Programing a cyanide-free transformation of aldehydes to nitriles and one-pot synthesis of amides through tandem chemo-enzymatic cascades.

Authors:  Haoteng Zheng; Qinjie Xiao; Feiying Mao; Anming Wang; Mu Li; Qiuyan Wang; Pengfei Zhang; Xiaolin Pei
Journal:  RSC Adv       Date:  2022-06-16       Impact factor: 4.036

  1 in total

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