Anaerobic hybrid membrane bioreactor for treatment of synthetic leachate: Impact of organic loading rate and sludge fractions on membrane fouling.

In the present study, the treatment of synthetic landfill leachate was carried out using a lab-scale anaerobic hybrid membrane bioreactor (An-HMBR). The reactor was operated for 250 days at two days of hydraulic retention time (HRT). Average chemical oxygen demand (COD) removal efficiency was ≥ 88% at steady-state conditions at 100% raw leachate. As organic loading rate (OLR) increased from 1.6 to 13.9 Kg COD m-3 d-1, flux gradually declined from 70 to 52 L/m2 h (LMH) within 250 days. Chemical membrane cleaning enhanced the flux up to 75% of the initial flux at the final stage of the reactor. Reversible fouling (>90%) dominated over irreversible fouling (<8%). Membrane fouling was mainly caused by extracellular polymeric substances (EPS) fraction, which resulted in cake layer formation on the ceramic membrane used in the An-HMBR system. Membrane resistance increased with variables in the following order OLR > MLSS (mixed liquor suspended solids) > EPS > SMP (soluble microbial products). A nonlinear regression model developed for prediction of membrane resistance at different OLR can predict with an error of ±7%.