Activated hydrochar produced from brewer's spent grain and its application in the removal of acetaminophen.

Acetaminophen has shown a gradual increase in detection in surface waters. Although present in low concentrations, it should be removed to prevent deleterious effects. Thus, adsorption onto activated carbon is emphasized. Adsorbents may be produced by hydrothermal carbonization (HTC), an environmental-friendly process. Therefore, this work aimed to investigate the use of HTC, verifying its application in acetaminophen removal. Brewer's spent grain (BSG), its hydrochar (HC-BSG) and its activated hydrochar (AHC-BSG) were characterized. HTC provided material with high carbon content. Lignocellulosic breakdown has been demonstrated in HC-BSG and AHC-BSG, but in the latter it was more intense as a result of activation with KOH. Also, a high surface area was found in AHC-BSG (1512.83 m2 g-1), resulting in an adsorption of 318.00 mg g-1. The pseudo-second-order and Langmuir models were fitted to the experimental data. Therefore, HTC was effective as a pretreatment for AHC-BSG, resulting in significant acetaminophen removals.