| Literature DB >> 32322865 |
Takumi Murata1, Mahoko Hiyoshi1, Manussada Ratanasak2, Jun-Ya Hasegawa2, Tadashi Ema1.
Abstract
Carbon dioxide (CO2) was used as a C1 source to prepare silyl formates, formamides, and aldehydes. Tetrabutylammonium acetate (TBAA) catalyzed the solvent-free N-formylation of amines with CO2 and hydrosilane to give formamides including Weinreb formamide, Me(MeO)NCHO, which was successively converted into aldehydes by one-pot reactions with Grignard reagents.Entities:
Year: 2020 PMID： 32322865 DOI： 10.1039/d0cc01371d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222