Literature DB >> 32286811

Activation of N2O and SO2 by the P-B Bond System. Reversible Binding of SO2 by the P-O-B Geminal Frustrated Lewis Pair.

Natalia Szynkiewicz1, Jarosław Chojnacki1, Rafał Grubba1.   

Abstract

Herein, we present the first transformation of n class="Chemical">borylphosphine into n class="Chemical">borylphosphinite using nitrous oxide. Borylphosphine reacts with N2O via insertion of a single oxygen atom into the P-B bond and formation of a P-O-B bond system. Borylphosphine and borylphosphinite capture SO2 and activate it in an irreversible and reversible manner, respectively.

Entities:  

Year:  2020        PMID： 32286811     DOI： 10.1021/acs.inorgchem.0c00435

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  Carbon dioxide reduction by an Al-O-P frustrated Lewis pair.

Authors:  Lucas Wickemeyer; Niklas Aders; Andreas Mix; Beate Neumann; Hans-Georg Stammler; Jorge J Cabrera-Trujillo; Israel Fernández; Norbert W Mitzel
Journal:  Chem Sci       Date:  2022-06-02       Impact factor: 9.969

2.  Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P-B-P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate.

Authors:  Natalia Szynkiewicz; Anna Ordyszewska; Jarosław Chojnacki; Rafał Grubba
Journal:  Inorg Chem       Date:  2021-03-03       Impact factor: 5.165

3.  Monomeric Triphosphinoboranes: Intramolecular Lewis Acid-Base Interactions between Boron and Phosphorus Atoms.

Authors:  Anna Ordyszewska; Natalia Szynkiewicz; Jarosław Chojnacki; Rafał Grubba
Journal:  Inorg Chem       Date:  2022-02-27       Impact factor: 5.165
  3 in total

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