Controlled Synthesis of Au Nanocrystals-Metal Selenide Hybrid Nanostructures toward Plasmon-Enhanced Photoelectrochemical Energy Conversion.

A simple method for the controllable synthesis of Au nanocrystals-metal selenide hybrid nanostructures via amino acid guiding strategy is proposed. The results show that the symmetric overgrowth mode of PbSe shells on Au nanorods can be precisely manipulated by only adjusting the initial concentration of Pb2+. The shape of Au-PbSe hybrids can evolve from dumbbell-like to yolk-shell. Interestingly, the plasmonic absorption enhancement could be tuned by the symmetry of these hybrid nanostructures. This provides an effective pathway for maneuvering plasmon-induced energy transfer in metal-semiconductor hybrids. In addition, the photoactivities of Au-PbSe nanorods sensitized TiO2 electrodes have been further evaluated. Owing to the synergism between effective plasmonic enhancement effect and efficient interfacial charge transfer in these hybrid nanostructures, the Au-PbSe yolk-shell nanorods exhibit an outstanding photocurrent activity. Their photocurrent density is 4.38 times larger than that of Au-PbSe dumbbell-like nanorods under light irradiation at λ > 600 nm. As a versatile method, the proposed strategy can also be employed to synthesize other metal-selenide hybrid nanostructures (such as Au-CdSe, Au-Bi2Se3 and Au-CuSe).