Zeolitic Imidazolate Framework-Based Composite Incorporated with Well-Dispersed CoNi Nanoparticles for Efficient Catalytic Reduction Reaction.

Incorporation of metal nanocatalysts within a well-defined porous support is of great importance for stabilizing unstable metal nanocatalysts, so that they display an effective and long-lasting catalytic activity. In particular, metal-organic frameworks (MOFs) with a wide range of structures serve as excellent porous supports for stabilizing unstable nanocatalysts. In addition, the development of inexpensive metal nanocatalysts is necessary to replace expensive noble metal nanocatalysts. Herein, we report on a simple method for the preparation of porous MOF-based or carbon-based composites incorporated with catalytically active CoNi alloy nanoparticles. CoNi alloy nanoparticles were produced from the concurrent reduction of Co and Ni ions existing within a zeolitic imidazolate framework (ZIF)-based precursor material during the thermal treatment. In particular, a part of the highly porous ZIF was preserved during the thermal treatment at 400 °C, which eventually resulted in a composite of ZIF and CoNi (CoNi@ZIF). The resulting CoNi@ZIF showed excellent catalytic activity for the reduction of 4-nitrophenol to 4-aminophenol. The synergy between the highly porous ZIF support and the well-dispersed CoNi nanoparticles within CoNi@ZIF provided an outstanding catalytic performance, even with inexpensive transition-metal nanocatalysts. Moreover, the catalytic activity of CoNi@ZIF was well conserved even after five consecutive reactions.