Literature DB >> 32236174

Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications.

Ülkü Kökçam-Demir1, Anna Goldman, Leili Esrafili, Maniya Gharib, Ali Morsali, Oliver Weingart, Christoph Janiak.   

Abstract

Metal-organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on the metal ions or cluster nodes have been generated. This review combines for the first time all aspects of OMS in MOFs, starting from different preparation strategies over theoretical studies on the effects of OMS with host-guest interactions up to distinct OMS-MOF applications. In the experimental part the focus of this review is on MOFs with proven OMS formation which are not only invoked but are clearly verified by analytical methods.

Entities:  

Year:  2020        PMID： 32236174     DOI： 10.1039/c9cs00609e

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  11 in total

1.  Catching the Reversible Formation and Reactivity of Surface Defective Sites in Metal-Organic Frameworks: An Operando Ambient Pressure-NEXAFS Investigation.

Authors:  Luca Braglia; Francesco Tavani; Silvia Mauri; Raju Edla; Damjan Krizmancic; Alessandro Tofoni; Valentina Colombo; Paola D'Angelo; Piero Torelli
Journal:  J Phys Chem Lett       Date:  2021-09-16       Impact factor: 6.888

2.  Thermal decarboxylation for the generation of hierarchical porosity in isostructural metal-organic frameworks containing open metal sites.

Authors:  Hannah F Drake; Zhifeng Xiao; Gregory S Day; Shaik Waseem Vali; Wenmiao Chen; Qi Wang; Yutao Huang; Tian-Hao Yan; Jason E Kuszynski; Paul A Lindahl; Matthew R Ryder; Hong-Cai Zhou
Journal:  Mater Adv       Date:  2021-07-14

3.  Selective and Fast Detection of Fluoride-Contaminated Water Based on a Novel Salen-Co-MOF Chemosensor.

Authors:  Maha Alhaddad; Said M El-Sheikh
Journal:  ACS Omega       Date:  2021-05-30

Review 4.  Emerging Porous Materials and Their Composites for NH3 Gas Removal.

Authors:  Dong Won Kang; Susan Eungyung Ju; Dae Won Kim; Minjung Kang; Hyojin Kim; Chang Seop Hong
Journal:  Adv Sci (Weinh)       Date:  2020-11-01       Impact factor: 16.806

5.  A series of four novel alkaline earth metal-organic frameworks constructed of Ca(ii), Sr(ii), Ba(ii) ions and tetrahedral MTB linker: structural diversity, stability study and low/high-pressure gas adsorption properties.

Authors:  Miroslav Almáši; Vladimír Zeleňák; Róbert Gyepes; Ľuboš Zauška; Sandrine Bourrelly
Journal:  RSC Adv       Date:  2020-09-01       Impact factor: 4.036

6.  Zinc(ii) and cadmium(ii) amorphous metal-organic frameworks (aMOFs): study of activation process and high-pressure adsorption of greenhouse gases.

Authors:  Miroslav Almáši; Nikolas Király; Vladimír Zeleňák; Mária Vilková; Sandrine Bourrelly
Journal:  RSC Adv       Date:  2021-06-04       Impact factor: 4.036

7.  High-performance and selective adsorption of ZIF-8/MIL-100 hybrids towards organic pollutants.

Authors:  Yukun Zhong; Xueliang Mu; U Kei Cheang
Journal:  Nanoscale Adv       Date:  2022-01-28

8.  Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity.

Authors:  Estitxu Echenique-Errandonea; Ricardo F Mendes; Flávio Figueira; Duane Choquesillo-Lazarte; Garikoitz Beobide; Javier Cepeda; Duarte Ananias; Antonio Rodríguez-Diéguez; Filipe A Almeida Paz; José M Seco
Journal:  Inorg Chem       Date:  2022-08-08       Impact factor: 5.436

9.  Efficient Removal of Chromium(VI) Anionic Species and Dye Anions from Water Using MOF-808 Materials Synthesized with the Assistance of Formic Acid.

Authors:  Khoa D Nguyen; Phuoc H Ho; Phuong D Vu; Thuyet L D Pham; Philippe Trens; Francesco Di Renzo; Nam T S Phan; Ha V Le
Journal:  Nanomaterials (Basel)       Date:  2021-05-25       Impact factor: 5.076

10.  Tailoring Lewis/Brønsted acid properties of MOF nodes via hydrothermal and solvothermal synthesis: simple approach with exceptional catalytic implications.

Authors:  Sergio Rojas-Buzo; Benjamin Bohigues; Christian W Lopes; Débora M Meira; Mercedes Boronat; Manuel Moliner; Avelino Corma
Journal:  Chem Sci       Date:  2021-07-05       Impact factor: 9.825
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