Upcycling of groundwater treatment sludge to an erdite nanorod as a highly effienct activation agent of peroxymonosulfate for wastewater treatment.

Groundwater treatment sludge is an Fe-rich waste continuously generated in large amounts through potable water production at groundwater treatment plants. In this study, the sludge was converted to erdite nanorod particles via a one-step hydrothermal route with only adding Na2S. The sludge was a mixture of ferrihydrite, hematite and Si/Al oxides. After hyddrothemal treatment, erdite was primarily formed from ferrihydrite, which accounted for 91.2% of the Fe species in the sludge, whereas approximately 8.8% of hematite accounted for the Fe species that remained before and after the reaction. The produced erdite nanorods were approximately 200 nm in diameter and 1-3 μm in length. They also exhibited a superior efficiency in peroxymonosulfate (PMS) activation. Nearly 100% quinoline removal (initail concentration = 10 mg L-1) was achieved when the eridite nanorods were used with PMS. The removal rate of quinoline was much higher than that of raw sludge, nano-scale zero-valent iron, FeS, hematite and magnetite. The erdite nanorods or the PMS alone had a quinoline removal rate of less than 20%. The erdite nanorods were spontaneously hydrolysed to generate Fe2+ for PMS activation and to form S species for the reductive cycling of Fe3+ to Fe2+, which likely promoted PMS activation. This study not only highlighted a facile method to recycle the sludge for erdite nanorod preparation but also presented a novel nanomaterial that could efficiently activate PMS for organic wastewater treatment.