Literature DB >> 32223400

Gradient and GENERIC time evolution towards reduced dynamics.

M Grmela1, V Klika2, M Pavelka3.   

Abstract

Reduction of a mesoscopic dynamical theory to equilibrium thermodynamics brings to the latter theory the fundamental thermodynamic relation (i.e. entropy as a function of the thermodynamic state variables). The reduction is made by following the mesoscopic time evolution to its conclusion, i.e. to fixed points at which the time evolution ceases to continue. The approach to fixed points is driven by entropy, that, if evaluated at the fixed points, becomes the thermodynamic entropy. Since the fixed points are parametrized by the thermodynamic state variables (by constants of motion), the thermodynamic entropy arises as a function of the thermodynamic state variables and thus the final outcome of the reduction is the fundamental thermodynamic relation. This reduction process extends also to reductions in which the reduced theory still involves the time evolution (e.g. reduction of kinetic theory to hydrodynamics). The essence of the extension is the replacement of the mesoscopic time evolution of the state variables with the corresponding mesoscopic time evolution of the vector field (i.e. of the fluxes). The fixed point in this flux time evolution is the vector field generating the reduced mesoscopic time evolution. The flux-entropy driving the flux time evolution becomes, if evaluated at the fixed point, the flux fundamental thermodynamic relation in the reduced dynamical theory. We show that the flux-entropy is a potential related to the entropy production. This article is part of the theme issue 'Fundamental aspects of nonequilibrium thermodynamics'.

Keywords:  GENERIC; multiscale thermodynamics; pattern recognition; reduction; vector fields

Year:  2020        PMID: 32223400      PMCID: PMC7134954          DOI: 10.1098/rsta.2019.0472

Source DB:  PubMed          Journal:  Philos Trans A Math Phys Eng Sci        ISSN: 1364-503X            Impact factor:   4.226


  6 in total

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  6 in total
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Journal:  Philos Trans A Math Phys Eng Sci       Date:  2020-03-30       Impact factor: 4.226

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Journal:  Philos Trans A Math Phys Eng Sci       Date:  2020-03-30       Impact factor: 4.226

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  5 in total

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