| Literature DB >> 32218266 |
Isabel Santamaría Vicario1, Lourdes Alameda Cuenca-Romero1, Sara Gutiérrez González1, Verónica Calderón Carpintero1, Ángel Rodríguez Saiz1.
Abstract
The properties and the behaviour of plaster mortars designed with Polyurethane Foam Waste (pan> class="Chemical">PFW) are studied in this investigation. A characterization of the mixtures is completed, in accordance with the technical specifications of European Norms. The incorporation of polyurethane waste foam can yield porous and lighter mortars, with better resistance to water-vapour permeability, although with weaker mechanical strength and higher levels of absorbency. Nevertheless, suitable mechanical strengths were achieved, resulting in a new material that is compliant with the requirements of the construction industry. The use of PFW in the the manufacture of gypsum mortars for construction reduces the consumption of natural resources and, at the same time, recovers an industrial waste that is otherwise difficult to recycle.Entities:
Keywords: gypsum mortar; polyurethane foam waste (PFW); recycled material; sustainable buildings
Year: 2020 PMID: 32218266 PMCID: PMC7177929 DOI: 10.3390/ma13071497
Source DB: PubMed Journal: Materials (Basel) ISSN: 1996-1944 Impact factor: 3.623
Properties of the gypsum conglomerates (Yesos Albi S.A.).
| A-1 | B-1 | |
|---|---|---|
| Granulometry | 0–2 mm | 0–2 mm |
| Purity index | >92.0% | — |
| Content in CaSO4 | >87.0% | >76.0% |
| Bending strength | >1.5 N/mm2 | >2.0 N/mm2 |
| Compressive strength | >3.5 N/mm2 | >3.0 N/mm2 |
| Water/Gypsum ratio | 0.66 | 0.40 |
| Onset of setting | >15 min | >20 min |
Figure 1Particle size distribution of polyurethane foam waste (PFW).
Chemical composition of Polyurethane Foam Waste (PFW).
| P (mg) | N (%) | C (%) | H (%) | S (%) | |
|---|---|---|---|---|---|
| PFW | 1.170 | 7.46 | 53.94 | 4.74 | 0.0 |
Figure 2Gypsum binder Type A1 (a); Gypsum binder Type B1 (c); PFW (b).
Mortar mixtures.
| Sample | Volume | Weigh (g) | |||||
|---|---|---|---|---|---|---|---|
| A1 | B1 | PFW | A1 | B1 | PFW | Water | |
| A1 | 1 | — | — | 1000 | — | — | 410.00 |
| A1:0.2PFW | 1 | — | 0.2 | 1000 | — | 22.23 | 454.89 |
| A1:0.4PFW | 1 | — | 0.4 | 1000 | — | 44.45 | 480.45 |
| A1:0.6PFW | 1 | — | 0.6 | 1000 | — | 66.68 | 533.34 |
| A1:PFW | 1 | — | 1 | 1000 | — | 111.14 | 677.80 |
| B1 | — | 1 | — | — | 1000 | — | 400.00 |
| B1:0.2PFW | — | 1 | 0.2 | — | 1000 | 17.51 | 432.44 |
| B1:0.4PFW | — | 1 | 0.4 | — | 1000 | 35.02 | 455.41 |
| B1:0.6PFW | — | 1 | 0.6 | — | 1000 | 52.53 | 510.48 |
| B1:PFW | — | 1 | 1 | — | 1000 | 87.55 | 636.22 |
Figure 3Shore C Durometer C (left); Flexural test (centre); Compressive test (right).
Characterization in the fresh state.
| Sample | w/b | Density | Onset of Setting Time | Onset of Setting Time |
|---|---|---|---|---|
| A1 | 0.410 | 1744 | 10:40 | 11 |
| A1:0.2PFW | 0.445 | 1719 | 09:33 | 10 |
| A1:0.4PFW | 0.460 | 1623 | 10:50 | 11 |
| A1:0.6PFW | 0.500 | 1615 | 12:10 | 12 |
| A1:PFW | 0.610 | 1510 | 12:25 | 12 |
| B1 | 0.400 | 1823 | 06:00 | 6 |
| B1:0.2PFW | 0.425 | 1771 | 07:00 | 7 |
| B1:0.4PFW | 0.440 | 1745 | 06:30 | 7 |
| B1:0.6PFW | 0.485 | 1667 | 07:30 | 8 |
| B1:PFW | 0.585 | 1536 | 09:45 | 10 |
Figure 4Bulk density of fresh mortar vs. w/b ratio.
Mechanical properties.
| Sample | Dry Bulk Density | Flexural Strength | Compressive Strength | Adherence Strength | Shore Hardness |
|---|---|---|---|---|---|
| A1 | 1443 | 8.48 | 22.38 | 1.08 | 93 |
| A1:0.2PFW | 1348 | 6.80 | 18.42 | 0.82 | 92 |
| A1:0.4PFW | 1299 | 5.82 | 16.47 | 0.72 | 92 |
| A1:0.6PFW | 1229 | 4.68 | 14.62 | 0.68 | 90 |
| A1:PFW | 1068 | 3.86 | 9.80 | 0.66 | 81 |
| B1 | 1485 | 7.70 | 20.54 | 1.05 | 95 |
| B1:0.2PFW | 1413 | 6.09 | 17.62 | 0.79 | 93 |
| B1:0.4PFW | 1371 | 5.59 | 15.04 | 0.59 | 92 |
| B1:0.6PFW | 1283 | 4.26 | 11.67 | 0.51 | 91 |
| B1:PFW | 1112 | 2.63 | 6.61 | 0.46 | 79 |
Figure 5Compressive strength vs. dry bulk density. Type A1 (a); Type B1 (b).
Figure 6Adherence test (left), height of water after 10 min of the suction test (right)
Mortar behaviour in the presence of water.
| Sample | Water Vapour Permeability | Water Absorption Due to Capillary Action | Total Water Absorption (%) | ||
|---|---|---|---|---|---|
| (kg/m·s·Pa) | µ | Coefficient (kg/m2·min0.5) | Height (mm)* | ||
| A1 | 3.7975 × 10−11 | 5 | 2.73 | 37 | 20.86 |
| A1:0.2PFW | 3.4754 × 10−11 | 5 | 2.79 | 44 | 23.11 |
| A1:0.4PFW | 4.3428 × 10−11 | 5 | 3.07 | 48 | 25.62 |
| A1:0.6PFW | 4.8993 × 10−11 | 4 | 3.33 | 49 | 29.34 |
| A1:PFW | 6.7349 × 10−11 | 3 | 3.80 | 56 | 38.99 |
| B1 | 2.8367 × 10−11 | 7 | 2.61 | 24 | 15.00 |
| B1:0.2PFW | 2.8570 × 10−11 | 7 | 2.64 | 28 | 16.58 |
| B1:0.4PFW | 2.7536 × 10−11 | 7 | 2.71 | 29 | 18.79 |
| B1:0.6PFW | 3.3085 × 10−11 | 6 | 3.09 | 34 | 23.53 |
| B1:PFW | 6.3198 × 10−11 | 3 | 3.89 | 43 | 32.38 |
* Water height at 10 min.