| Literature DB >> 32201870 |
Christopher L Anderson1, Jiatao Liang1, Simon J Teat2, Andrés Garzón-Ruiz3, David P Nenon4, Amparo Navarro5, Yi Liu6.
Abstract
The generation of a highly-substituted [2.2](2,5)pyrazinophane via a cascade reaction is presented. The pyrazinophane product is formed via the dimerization of a member of the para-azaquinodimethane (p-AQM) family of conjugated quinoidal compounds-reactivity that sheds light on the nature of stability in p-AQMs. Additionally, the electronic and structural nature of this highly-strained ring system are characterized.Entities:
Year: 2020 PMID： 32201870 DOI： 10.1039/d0cc00916d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222