| Literature DB >> 32159964 |
Juha H Siitonen1, Padmanabha V Kattamuri1, Muhammed Yousufuddin2, László Kürti1.
Abstract
O-Unprotected keto- and aldoximes are readily C-allylated with allyl diisopropyl boronate in the presence of arylboronic acid catalysts to yield highly substituted N-α-secondary and tertiary homoallylic hydroxylamines. The method was used in the total synthesis of the trace alkaloid N-Me-Euphococcine.Entities:
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Year: 2020 PMID： 32159964 DOI： 10.1021/acs.orglett.0c00727
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005