Investigation of the Thermal Conductivity of Resin-Based Lightweight Composites Filled with Hollow Glass Microspheres.

The design and development of thermal insulation materials is very important for the treatment of offshore oil pipelines. Understanding thermal energy transport in thermal insulation materials and predicting their thermal conductivities have important theoretical and practical value for the design of thermal insulation materials. In this work, lightweight and thermally insulated (LWTI) composites with the desired mechanical strength for offshore oil pipelines applications were prepared using epoxy resin (EP) as the matrix and hollow glass microspheres (HGMs) as the filler. The morphology, density, and mechanical properties of HGM/EP LWTI composites were studied first. The flexural strength and the flexural modulus of HGM/EP LWTI composites could still be as high as 22.34 ± 2.75 Mpa and 1.34 ± 0.03 GPa, respectively, while the density was only 0.591 g/cm3. The relationship between the effective thermal conductivity of HGM/EP LWTI composites and material parameters (sizes and contents together) has been studied systematically. A three-phase prediction model was built using the self-consistent approximation method to predict the effective thermal conductivity of HGM/EP LWTI composites, and the resin matrix, the wall thickness, the HGM particle size, and other parameters (such as air) were fully considered during the derivation of this three-phase thermal conductivity model. Finally, the insulation mechanism of HGM/EP LWTI composites was systematically analyzed. The thermal conductivities of HGM/EP LWTI composites with different diameters and HGM contents calculated by the three-phase prediction model agreed well with the experimental test results, with a minimum error of only 0.69%. Thus, this three-phase thermal conductivity model can be used to theoretically simulate the thermal conductivity of epoxy resin-based LWTI composites and can be the theoretical basis for the design and prediction of the thermal conductivity of other similar hollow spheres filled materials.