Literature DB >> 32115593

Expanding the BN-embedded PAH family: 4a-aza-12a-borachrysene.

Alberto Abengózar1, Isabel Valencia1, Guillermo G Otárola1, David Sucunza1, Patricia García-García1, Adrián Pérez-Redondo1, Francisco Mendicuti2, Juan J Vaquero1.   

Abstract

Previously unknown 4a-aza-12a-borachrysene has been synthesized in only four steps. The reactions of this BN-embedded PAH with bromine and organolithium compounds proceed with complete regioselectivity, resulting in the formation of nine derivatives. One of these, a phenylalkynyl-substituted derivative, exhibits a remarkably high fluorescence quantum yield (ΦF = 0.68).

Entities:  

Year:  2020        PMID: 32115593     DOI: 10.1039/c9cc09998k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Going beyond the borders: pyrrolo[3,2-b]pyrroles with deep red emission.

Authors:  Mariusz Tasior; Paweł Kowalczyk; Marta Przybył; Małgorzata Czichy; Patryk Janasik; Manon H E Bousquet; Mieczysław Łapkowski; Matt Rammo; Aleksander Rebane; Denis Jacquemin; Daniel T Gryko
Journal:  Chem Sci       Date:  2021-11-22       Impact factor: 9.825

2.  1,10a-Dihydro-1-aza-10a-boraphenanthrene and 6a,7-Dihydro-7-aza-6a-boratetraphene: Two New Fluorescent BN-PAHs.

Authors:  Isabel Valencia; Patricia García-García; David Sucunza; Francisco Mendicuti; Juan J Vaquero
Journal:  J Org Chem       Date:  2021-11-22       Impact factor: 4.354

3.  Synthesis of BN-Polyarenes by a Mild Borylative Cyclization Cascade.

Authors:  Ester Sans-Panadés; Juan J Vaquero; Manuel A Fernández-Rodríguez; Patricia García-García
Journal:  Org Lett       Date:  2022-08-01       Impact factor: 6.072

  3 in total

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