Core-shell Au@Pt Nanoparticles Catalyzed Luminol Chemiluminescence for Sensitive Detection of Thiocyanate.

In this study, core-shell Au@Pt nanoparticles (Au@Pt NPs) with peroxidase catalytic activity were synthesized by the seed-mediated method, and were used to catalyze the reaction of luminol-H2O2 to enhance the chemiluminescence (CL) intensity. It was found that thiocyanate (SCN-) can effectively inhibit the catalytic activity of Au@Pt NPs. Based on this phenomenon, a method to detect SCN- by using the Au@Pt NPs-catalytic luminol-H2O2 CL system was established, which has an ultra-low detection limit and an ultra-wide linear range, as well as the advantages of being simple and having low-cost and convenient operation. The research mechanism indicated that SCN- could be adsorbed on the surface of Au@Pt NPs and occupies the active sites of Pt nanostructures, which led to a decrease in the amount of Pt0 and a loss of the excellent catalytic activity of Au@Pt NPs. After optimizing the experimental conditions, this assay for detecting SCN- exhibited a good linear range from 5 to 180 nM, and the low detection limit was 2.9 nM. In addition, this approach has been successfully applied to the detection of SCN- in tap-water samples, which has practical application value and embodies good development prospects.