Nanomaterials in speciation analysis of metals and metalloids.

Nanomaterials have draw extensive attention from the scientists in recent years mainly due to their unique and attractive thermal, mechanical and electronic properties, as well as high surface to volume ratio and the possibility for surface functionalization. Whereas mono functional nanomaterials providing a single function, the preparation of core/shell nanoparticles allows different properties to be combined in one material. Their properties have been extensively exploited in different extraction techniques to improve the efficiency of separation and preconcentration, analytical selectivity and method reliability. The aim of this paper is to provide an updated revision of the most important features and application of nanomaterials (metallic, silica, polymeric and carbon-based) for solid phase extraction and microextraction techniques in speciation analysis of some metals and metalloids (As, Cr, Sb, Se). Emphasis will be placed on the presentation of the most representative works published in the last five years (2015-2019).