Literature DB >> 32104842

Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes.

Mainak Das1, Sangya Chitranshi1, M Murugavel1, B Adinarayana1, Cherumuttathu H Suresh2, A Srinivasan1.   

Abstract

Isosmaragdyrin with an N3C2 core is successfully achieved by introducing a 2,6-di-m-phenylpyridine unit. The core is utilized to stabilize the Rh(i) ion in the N-Rh(i)-N bonding mode and the Pt(ii) ion in the (N^C)N fashion to form an unsymmetrical pincer-type organometallic complex.

Entities:  

Year:  2020        PMID： 32104842     DOI： 10.1039/d0cc00214c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Recent Advances in the Design and Syntheses of Porphyrinoids by Embedding Higher Analogues of Arene and Pyridine Units.

Authors:  Mainak Das; B Adinarayana; A Srinivasan
Journal:  ACS Omega       Date:  2021-12-13

2.  Kinetic trapping of a cobalt(ii) metallocage using a carbazole-containing expanded carbaporphyrinoid ligand.

Authors:  Weinan Zhou; Tridib Sarma; Yonghuan Su; Chuanhu Lei; Jonathan L Sessler
Journal:  Chem Sci       Date:  2021-12-20       Impact factor: 9.825
  2 in total

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