Nanofiber NiMoO4/g-C3N4 Composite Electrode Materials for Redox Supercapacitor Applications.

NiMoO4/g-C3N4 was fabricated by a hydrothermal method and used as an electrode material in a supercapacitor. The samples were characterized by XRD, FTIR, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) to study the physical and structural properties of the as-prepared NiMoO4/g-C3N4 material. The electrochemical responses of pristine NiMoO4 and the NiMoO4/g-C3N4 nanocomposite material were investigated by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS). From the CD studies, the NiMoO4/g-C3N4 nanocomposite revealed a higher maximum specific capacitance (510 Fg-1) in comparison to pristine NiMoO4 (203 Fg-1). In addition, the NiMoO4/g-C3N4 composite electrode material exhibited high stability, which maintained up to 91.8% capacity even after 2000 charge-discharge cycles. Finally, NiMoO4/g-C3N4 was found to exhibit an energy density value of 11.3 Whkg-1. These findings clearly suggested that NiMoO4/g-C3N4 could be a suitable electrode material for electrochemical capacitors.

1. Introduction

Owing to the environmental pollution caused by the emission of greenhouse gases from fossil fuels, researchers have been developing renewable energy sources for which new types of energy storage devices, such as fuel cells, batteries, conventional capacitors and electrochemical supercapacitors are required [1]. Among the numerous types of energy storage devices, supercapacitors are one of the most appropriate ESDs (energy storage devices), owing to their superior power density, fast reversible/irreversible time, long life span and low cost [2,3,4]. Supercapacitors are also known as new electrochemical capacitors or ultracapacitors. According to the storage phenomenon of the supercapacitor, they can be categorized as electrical double-layer capacitance (EDLCs) or pseudocapacitors. EDLCs store charges through the electrode and electrolyte interface by a diffusion/charge accumulation process, whereas in pseudocapacitors, the charges are stored through Faradaic processes (occurring in the active material) and electrolytes (during the redox reactions), thus displaying higher specific capacitance (SC) values than those seen for EDLCs [5].

Carbon-based composite materials, namely n class="Chemical">graphene, activated carbon, carbon aerogel, carbon nanotubes and carbon cloth, are the most used electrode materials in EDLCs [3,6], whereas transition metal oxides/hydroxides are used as electrode materials in pseudocapacitors. These metal oxides have attracted the attention of researchers owing to their significant characteristics such as high SC values, high power density and energy density, as well as rapid and reversible redox reactions at the electrode/electrolyte surfaces [7,8]. Efficient transition metal oxides and hydroxides reported so far include RuO2 [9], MnO2 [10], Co(OH)2 [11], NiO [12] and WO3 [13].

In recent years, ESD research has focused on metal molybdates, owing to their advantageous properties [14,15], one of which is the extensive research carried out around n class="Chemical">NiMoO4 owing to its enhanced electrochemical properties. Guo et al. [16] developed NiMoO4 nanowires loaded on a Ni foam electrode that delivered a superior SC of 1308 Fg−1 at 74.7 Ag−1. Likewise, Lin et al. [17] developed groove-like NiMoO4 hollow nanorods for high-performance supercapacitors, and the electrodes had a high SC of 1102 Fg−1 at a current density of 1 Ag−1. Senthilkumar et al. [18] synthesized nano α-NiMoO4 as a new electrode material for supercapacitors and calculated the SC at a current density of 1.2 Ag−1 as 1517 Fg−1. Jothi et al. [19] reported the synthesis of 1D α-NiMoO4 nanorods electrode materials for supercapacitors and found the maximum SC obtained from the electrochemical measurement was 730 Fg−1 at a scan rate of 5 mVs−1. Wang et al. [20] developed carbon-sheathed NiMoO4 nanowires loaded onto a Ni foam as an electrode material for supercapacitors, which exhibited maximal SC of 3070 Fg−1 at 2.5 Ag−1. Liu et al. [21] synthesized CoMoO4-NiMoO4·xH2O bundles by a simple coprecipitation method, which exhibited a maximum SC value of 1039 Fg−1 at a current density of 2.5 mAcm−2. In another study, Senthilkumar et al. [22] synthesized nanostructured β-NiMoO4-CoMoO4·xH2O composites through a solution combustion process, which exhibited an exceptional SC of 1472 Fg−1 at 5 mAcm−2. Ren et al. [23] synthesized NiMoO4@Co(OH)2 core-shell structured nanowire arrays by means of a hydrothermal process and an electrodeposition method route that led to a maximal SC value of 2122 Fg−1 at 4.5 Ag−1. In this present study, we also chose NiMoO4 as one of the electrode components. However, we coupled NiMoO4 with g-C3N4, one of the most widely investigated potential material for photocatalysis and other energy conversion devices [24,25,26]. Zhang et al. [27] prepared 3D RuO2/g‑C3N4@rGO aerogel composites for SCs that revealed a maximum SC value of 704.3 Fg−1 at 0.5 Ag−1. This study further addressed the potential applications of this strategy in developing 3D rGO aerogel composite for high-performance supercapacitors. Moreover, Zhang et al. [28] also developed Ni2P2O7 nanoarrays with the incorporation of g-C3N4 to yield efficient electrode materials, which retained 91% of SC efficiency after 1000 cycles.

Herein, we report for the first time the synthesis of NiMoO4/g-C3N4 by a hydrothermal method and its suitability as an electrode material for supercapacitors. It was found that the optimized NiMoO4/g-C3N4 composite coated on a carbon paper delivered a high SC value with superior cyclic stability, which could serve as a potential candidate for pseudocapacitor applications.

2. Experimental Section

2.1. Preparation of g-C3N4

The synthesis of g-C3N4 proceeded through a thermal polycondensation of urea. Typically, 6 g of urea was added in an alumina crucible (with a lid in order to avoid sublimation), followed by annealing at 500 °C for 2 h. After cooling naturally, a yellow material was obtained.

2.2. Preparation of NiMoO4/g-C3N4 by Hydrothermal Method

In double distilled (DD) water (40 mL), 3 mM of Na2MoO4·7H2O and 3 mM of NiCl2·6H2O (SDFCL, Mumbai, India) were dispersed, and then placed in an ultrasonic bath (42 kHz) for 30 min. A second solution was prepared by dispersing 10 mg of n class="Chemical">g-C3N4 in 20 mL DD water and was placed in an ultrasonic bath for 60 min. The two different solutions were poured into a Teflon-lined autoclave and annealed at 140 °C for 12 h. After this process, the autoclave was left to cool down. The sample was filtered and cleaned several times with DD water, followed by ethyl alcohol (at least three times). The obtained powder was dried overnight and annealed at 500 °C for 4 h. The mass ratio of g-C3N4 in the NiMoO4/g-C3N4 nanocomposite was 10 wt.%. The same method was followed to produce a pristine NiMoO4 nanomaterial without the addition of the g-C3N4 solution.

2.3. Preparation of Electrode Material

The electrode materials were fabricated by mixing either NiMoO4 or NiMoO4/g-C3N4(80%), polyvinylidine fluoride (Sigma Aldrich, St. Louis, MI, USA), a binder (10%) and a super P black (10%) conducting material (Timcal, Bironico, Switzerland) in the solvent 1-methyl-2-pyrrolidone until the slurry became a fine paste. The paste was then uniformly loaded on a carbon paper (surface area approximately 0.5 cm2) and dried at 80 °C overnight. The amount of electrode material was approximately 1 mg.

2.4. Electrochemical Measurements

The electrochemical properties of NiMoO4 and n class="Chemical">NiMoO4/g-C3N4 samples were assessed by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). All electrochemical experiments were performed using an electrochemical system (CHI608E, USA) in a standard 3-electrode assembly using Ag/AgCl as a reference electrode, a Pt wire as a counter electrode (diameter of 0.5 mm, and length of 5 cm), and either the NiMoO4 or NiMoO4/g-C3N4 active material loaded onto carbon paper as a working electrode. A 6 M KOH alkaline solution was used as the electrolyte solution. The CV analyses were performed using an applied potential with a range from +0.1 V vs. Ag/AgCl to +0.55 V vs. Ag/AgCl, and the GCD analyses were performed in the potential range from +0.1 V vs. Ag/AgCl to +0.5 V vs. Ag/AgCl. The SC values were evaluated from the CVs, as described in [18]. The SC values of the NiMoO4 and NiMoO4/g-C3N4 electrode were evaluated based on GCD using Equation (1) [29], in which I is the discharging current, t is discharged time, m is the amount of loaded electrode materials and ΔV is the applied potential difference.

3. Results and Discussion

3.1. XRD Analysis

The XRD patterns obtained for the NiMoO4, n class="Chemical">g-C3N4, and NiMoO4/g-C3N4 samples are displayed in Figure 1a–c. Figure 1a shows the diffraction lines derived from 2θ values of pristine NiMoO4 namely; 14.3°, 19.0°, 23.8°, 25.4°, 26.8°, 28.8°, 32.6°, 34.2°, 38.5°, 41.1°, 43.9°, 47.5°, 53.4°, 56.2°, 57.8°, 62.0° and 66.4°. These Bragg angles are in good agreement with JCPDS No. 45-0142, according to a monoclinic phase. The XRD of g-C3N4 exhibited two diffraction peaks at 2θ values 13.06° and 27.4°, which are assigned to the (100) and (002) planes of hexagonal g-C3N4 (JCPDS card No. 87-1526). Thus, the peaks which appeared at 13.06° and 27.4° are corresponding to the in-plane structural design and the interlayer stacking of the aromatic part of g-C3N4 [30]. The NiMoO4/g-C3N4 nanocomposite has a similar XRD pattern to that of pristine NiMoO4, which can be owing to the untraceable amount of g-C3N4 present in the composite. However, it can be observed that the peak intensity of NiMoO4/g-C3N4 is increased by the addition of g-C3N4. Hence, the obtained XRD results support the formation of a NiMoO4/g-C3N4 composite.

Figure 1

X-ray diffraction spectra of (a) NiMoO4, (b) g-C3N4 and (c) NiMoO4/g-C3N4.

3.2. Fourier Transform Infrared (FTIR) Spectroscopy

FTIR spectra of the as-prepared NiMoO4, n class="Chemical">g-C3N4, and NiMoO4/g-C3N4 active electrode materials are illustrated in Figure 2. Of interest are the observed vibrational bands at 975 and 862 cm−1, which correspond to the symmetric and antisymmetric stretching vibrations of the Mo-O [31] linkage. The absorbance band at approximately 606 cm−1 corresponds to the stretching vibration of Ni-O [32]. Pure g-C3N4 demonstrates a strong band around 3100–3300 cm−1, corresponding to the stretching modes of N–H bonds (–NH3 and =NH) of amines [33]. Furthermore, the broad peaks observed in the range of 1200–1680 cm−1 are related to the stretching modes of C=N and the heterocyclic aromatic C–N bonds [34]. Moreover, the peak appearing at 811 cm−1 is a distinctive breathing mode of triazine units. In the case of NiMoO4/g-C3N4, an increase in the absorbance bands when g-C3N4 was added to NiMoO4 can be observed, indicating the coexistence of the NiMoO4 and g-C3N4 in the composite material, which the XRD data also supports.

Figure 2

FTIR spectra of NiMoO4, g-C3N4 and NiMoO4/g-C3N4.

3.3. Surface Morphology and Elemental Studies

The morphological characteristics of g-C3N4, n class="Chemical">NiMoO4, and NiMoO4/g-C3N4 were investigated by scanning electron microscopy (SEM). Characteristic SEM micrographs of g-C3N4, NiMoO4, and NiMoO4/g-C3N4 are displayed in Figure 3. The pristine NiMoO4 shows a “sponge with fiber”-like morphology, whereas pure g-C3N4 appears as aggregated particles containing a nanosheet-like morphology. The NiMoO4/g-C3N4 composite exhibits clear nanofiber-like structure (Figure 3c,d). Figure 4 displays the energy dispersive X-ray microanalysis (EDAX) spectrum of NiMoO4/g-C3N4 composite material. The peaks corresponding to Ni, Mo, O, C and N are present with no other peaks observed, indicating the high purity of the as-prepared NiMoO4/g-C3N4 composite. The corresponding atomic (%) ratios of the elements identified by the EDAX spectrum are shown in the inset of Figure 4. The XRD and EDAX results clearly indicate the formation of a NiMoO4/g-C3N4 composite. To further confirm the morphology of the NiMoO4/g-C3N4 composite, transition electron microscopy (TEM) was performed (Figure 5). The TEM images clearly inferred that the morphology of NiMoO4/g-C3N4 composite is of a nanofiber-like structure within a size range of 100 to 200 nm and is attached to the sheet-like structure of g-C3N4. In comparison with pure NiMoO4, the NiMoO4/g-C3N4 composite possesses a clear nanofiber structure, which is favorable for redox reactions. The TEM morphological analyses support the SEM analyses.

Figure 3

SEM analysis of (a) g-C3N4, (b) NiMoO4 and (c,d) NiMoO4/g-C3N4 samples.

Figure 4

The EDAX spectrum of NiMoO4/g-C3N4 composite.

Figure 5

TEM analysis of (a,b) NiMoO4/g-C3N4 composite.

3.4. CV Studies

The electrochemical responses of the as-prepared materials were evaluated under CV measurements. Figure 6a shows the CV curves for pristine NiMoO4 and n class="Chemical">NiMoO4/g-C3N4 at a scan rate of 10 mVs−1. Both electrode materials exhibit clear redox peaks with the NiMoO4/g-C3N4 electrode material possessing the highest redox peak current value (the peak current values for pure, pristine NiMoO4 and NiMoO4/g-C3N4 are 0.011 and 0.015 A at 10 mVs−1, respectively), clearly indicating that an improvement in electrochemical performance exists. Figure 6b,c shows the CV curves of pristine NiMoO4 and NiMoO4/g-C3N4 at different scan rates of 5 to 40 mVs−1. Notably, as the scan rate increases, the anodic and cathodic peak currents increase, and the anodic and cathodic peak potentials shift. This observation is owing to a sluggish ionic diffusion rate preventing electronic neutralization in the Faradaic redox reaction [35]. Figure 6d shows the difference in SC of both the pristine and composite at various scan rates.

Figure 6

(a) Comparison of CV curves of pristine NiMoO4 and NiMoO4/g-C3N4 at a scan rate of 10 mVs−1, (b,c) CV curves of pure NiMoO4 and composite materials at several scan rates, and (d) its corresponding plot of SC with scan rates.

3.5. GCD Studies

The GCD performance can be used to identify the stability and time reversibility of the electrode material. The comparison of n class="Chemical">GCD curves for NiMoO4 and NiMoO4/g-C3N4 is displayed in Figure 7a. From the GCD curves, it can be observed that the NiMoO4/g-C3N4 has a higher reversible time than that of NiMoO4. The calculated SC values of pristine NiMoO4 and NiMoO4/g-C3N4 were found to be 203 and 510 Fg−1 at a current of 1 Ag−1, respectively. Figure 7b,c illustrates the GCD curves of NiMoO4 and NiMoO4/g-C3N4 at several currents from 1 to 9 Ag−1. Figure 7d shows the variation of SC with respect to the current. Figure 8 shows the long-term cyclic test of the NiMoO4/g-C3N4 composite electrode material up to 2000 cycles. It can be shown that the NiMoO4/g-C3N4 electrode material retained approximately 91.8% of the SC value after 2000 cycles in comparison with its initial capacitance value. The generated results from the stability test showed that the initial SC value of 342.5 Fg−1 gradually increased up to 650 cycles with an SC value of 395 Fg−1. In other words, the SC value increased 115% from its initial capacitance value, probably owing to the increased number of active sites available for the electrochemical reactions [36]. The calculated coulombic efficiency was also found to be nearly 100% after 2000 cycles. According to the CV and GCD data, it can be deduced that the NiMoO4/g-C3N4 composite is a suitable electrode material for pseudocapacitor applications.

Figure 7

(a) Comparative GCD plots of the pristine NiMoO4 and NiMoO4/g-C3N4 nanocomposite electrodes at a current of 1 Ag−1, (b,c) GCD curves of the pristine NiMoO4 and NiMoO4/g-C3N4 nanocomposite at various current densities, and (d) its corresponding plot of SC with related to current densities.

Figure 8

Specific capacitance vs. cycle number and coulombic efficiency vs. cycle number plot of NiMoO4/g-C3N4 nanocomposite electrode.

The energy density (E) and power density (P) for pseudocapacitors can be calculated from Equations (2) and (3), respectively [37]. where C is the SC, ∆V is potential used in the GCD measurement, and ∆td is the discharge time (s). The calculated E and P values of pristine n class="Chemical">NiMoO4 and NiMoO4/g-C3N4 were found to be 4.5 and 11.3 Wh kg−1, respectively.

Figure 9 shows a linear relationship between the anodic and the cathodic peak currents (Ipa.c), and the square root of the scan rate (values extracted from Figure 6). It is observed that the anodic and cathodic peak currents of NiMoO4 and the n class="Chemical">NiMoO4/g-C3N4 composite follow the Randles–Sevcik equation (Equation (4)) [29], where n is the number of electrons transferred through reaction, A is the working electrode surface area, D is the diffusion coefficient, C is the electrolyte concentration, and v is the scan rate. The Randles–Sevcik equation describes the effect of the scan rate on the anodic or cathodic peak current Ipa,c in the redox process. Generally, it depends not only on the concentration of the electrolyte but on the diffusional properties of the electrode material and on the scan rate [38,39].

Figure 9

The linear dependence between the cyclic voltammetric anodic and cathodic peak current and the square root of the various scan rates of pristine NiMoO4 and NiMoO4/g-C3N4 composite.

The diffusion coefficient of pristine NiMoO4 and NiMoO4/g-C3N4 composite was calculated as 1.539 × 10−8 and 3.463 × 10−8 cm2s−1, respectively. The achieved diffusion coefficient values clearly show that the NiMoO4/g-C3N4 composite has a higher value than that of the pristine NiMoO4. This is supported by the CV and the GCD results of the NiMoO4/g-C3N4 nanomaterial.

3.6. EIS Studies

EIS is an important method to describe the interfacial resistance and the charge-transfer (CT) performance of active materials. Additionally, it can also reveal the pseudocapacitance (Cp), double-layer capacitance (Cdl), bulk resistance (n class="Chemical">Rb), CT resistance (Rct) and the series resistance (Rs) that is associated with the summation of the electrode/electrolyte interfacial resistance [40]. The EIS studies for pristine NiMoO4 and the NiMoO4/g-C3N4 composite material were carried out in a frequency ranging from 105 Hz to 1 Hz at an amplitude of +0.005 V. The Nyquist plots are illustrated in Figure 10 (the figure inset shows the consequent equivalent circuit model). The impedance spectra in Figure 9 show a semi-circle pattern at higher frequencies and a straight line at lower frequencies. The occurrence of a semi-circle corresponds to the Faradaic redox reaction that occurs on the active material coated area of the pristine NiMoO4 and NiMoO4/g-C3N4 composite. The calculated resistance values are shown in Table 1. The calculated Rct values for pristine NiMoO4 and NiMoO4/g-C3N4 composite were found to be 0.047 and 0.042 Ω, respectively. From Table 1, it is evident that the NiMoO4/g-C3N4 composite exhibited a lower Rct value than that of the pristine NiMoO4. Furthermore, the EIS results also support CV and GCD results.

Figure 10

Nyquist plots of pristine NiMoO4 and NiMoO4/g-C3N4 electrode materials (inset figure showing the zoomed view of the Nyquist plot).

Table 1

Rs, Rct and Rb values of the pure NiMoO4 and NiMoO4/g-C3N4 composite.

Sample	Rs (Ω)	Rct (Ω)	Rb (Ω)
NiMoO4	2.260	0.047	2.307
NiMoO4/g-C3N4	2.212	0.042	2.264

4. Conclusions

NiMoO4/n class="Chemical">g-C3N4 composite nanofibers were successfully synthesized using a hydrothermal route. The phase purity and surface morphology were examined by XRD, FTIR, SEM and EDAX analysis. The electrochemical performance of pristine NiMoO4 and NiMoO4/g-C3N4 composite materials were evaluated and compared using CV, GCD and EIS studies. The calculated SC value of NiMoO4/g-C3N4 composite was found to be 510 Fg−1, whereas pristine NiMoO4 had a value of 210 Fg−1 at a current 1 Ag−1. The NiMoO4/g-C3N4 composite electrode material was subjected to a long-term stability test, and it was found that the as-prepared materials withstood up to 91.8% retention from its initial capacitance value of the charge-discharge curves even after 2000 cycles at a current of 5 Ag−1. The NiMoO4/g-C3N4 composite material was found to have a higher energy density value (11.3 Wh kg−1) than that of the pristine NiMoO4 (4.5 Wh kg−1). From the SC results, the NiMoO4/g-C3N4 composite could be potentially used as a supercapacitor electrode material.