Inkjet printing assisted fabrication of polyphenol-based coating membranes for oil/water separation.

While polyphenol-based coating has been regarded as a promising alternative to functionalize membrane surface, it usually suffers from problems of low-efficient procedure and low utilization rate of the polyphenolic compounds, hindering its large-scale implementations. To solve these problems, this study provided a first report on inkjet printing of polyphenols (catechol (CA) or tannic acid (TA)) and sodium periodate (SP) on a polyvinylidene fluoride (PVDF) membrane to improve membrane performance. A series of analyses showed the efficient formation of homogenous films on the PVDF membrane surface and the improvement of hydrophilicity by the inkjet printing technique. The PVDF membranes decorated with the optimized polyphenolic coating exhibited a promising oil/water separation efficiency (higher than 99%) with a high average water permeation flux of 5.2 times higher than that of the pristine membrane. Meanwhile, the modified membranes illustrated a good stability under acidic conditions (pH = 2-7). The novel method proposed in this study is facile, cost-saving and environment-friendly. The advantages of the proposed method and the modified membranes demonstrated the great significance of the proposed method in practical applications.