Literature DB >> 32026890

Effect of copper salts on hydrothermal oxidative decarboxylation: a study of phenylacetic acid.

Xuan Fu1, Megan Jamison, Aaron M Jubb, Yiju Liao, Alexandria Aspin, Kyle Hayes, Christopher R Glein, Ziming Yang.   

Abstract

Decarboxylation of carboxylic acids is favored under hydrothermal conditions, and can be influenced by dissolved metals. Here, we use phenylacetic acid as a model compound to study its hydrothermal decarboxylation in the presence of copper(ii) salts but no O2. Our results showed a strong oxidizing role of copper in facilitating oxidative decarboxylation.

Entities:  

Year:  2020        PMID: 32026890     DOI: 10.1039/c9cc09825a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Anaerobic oxidation of aldehydes to carboxylic acids under hydrothermal conditions.

Authors:  Yiju Liao; Alexandria Aspin; Ziming Yang
Journal:  RSC Adv       Date:  2022-01-11       Impact factor: 3.361

  1 in total

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