Literature DB >> 32016211

Thiocyanate complexes of the lanthanides, Am and Cm.

Richard E Wilson1, Tyler J Carter, Matthieu Autillo, Samantha Stegman.   

Abstract

The synthesis and single crystal structures of Am(iii) and Cm(iii) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal-thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal-ligand interactions.

Entities:  

Year:  2020        PMID： 32016211     DOI： 10.1039/c9cc07612c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  In situ beam reduction of Pu(IV) and Bk(IV) as a route to trivalent transuranic coordination complexes with hydroxypyridinone chelators.

Authors:  Korey P Carter; Jennifer N Wacker; Kurt F Smith; Gauthier J P Deblonde; Liane M Moreau; Julian A Rees; Corwin H Booth; Rebecca J Abergel
Journal:  J Synchrotron Radiat       Date:  2022-02-25       Impact factor: 2.616

2.  Carbene Complexes of Neptunium.

Authors:  Conrad A P Goodwin; Ashley J Wooles; Jesse Murillo; Erli Lu; Josef T Boronski; Brian L Scott; Andrew J Gaunt; Stephen T Liddle
Journal:  J Am Chem Soc       Date:  2022-05-24       Impact factor: 16.383
  2 in total

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