Literature DB >> 32011095

N-Centered Radical Directed Remote C-H Bond Functionalization via Hydrogen Atom Transfer.

Gautam Kumar1, Suman Pradhan1, Indranil Chatterjee1.   

Abstract

The N-centered radical directed remote C-H bond functionalization via hydrogen-atom-transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C-H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days' developments in this field of unactivated remote C-H bonds functionalizations.
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−N/C−C bond formation; N-centered radical; heterocycles; hydrogen atom transfer; remote functionalization

Year:  2020        PMID: 32011095     DOI: 10.1002/asia.201901744

Source DB:  PubMed          Journal:  Chem Asian J        ISSN: 1861-471X


  8 in total

1.  Aza-Heterocycles via Copper-Catalyzed, Remote C-H Desaturation of Amines.

Authors:  Leah M Stateman; Ross M Dare; Alyson N Paneque; David A Nagib
Journal:  Chem       Date:  2021-11-16       Impact factor: 22.804

2.  Iminyl radical-triggered relay annulation for the construction of bridged aza-tetracycles bearing four contiguous stereogenic centers.

Authors:  Kun Jiang; Shi-Jun Li; Qing-Peng Liu; Ning Yu; Yu-Lin Li; Yu-Qiang Zhou; Kui-Cheng He; Jing Lin; Ting-Yu Zheng; Jian Lang; Yu Lan; Ye Wei
Journal:  Chem Sci       Date:  2022-05-30       Impact factor: 9.969

Review 3.  Recent Advances in Photoredox-Mediated Radical Conjugate Addition Reactions: An Expanding Toolkit for the Giese Reaction.

Authors:  Anastasia L Gant Kanegusuku; Jennifer L Roizen
Journal:  Angew Chem Int Ed Engl       Date:  2021-07-21       Impact factor: 16.823

4.  Remote Radical Desaturation of Unactivated C-H Bonds in Amides.

Authors:  Yong Xia; Kalipada Jana; Armido Studer
Journal:  Chemistry       Date:  2021-10-08       Impact factor: 5.020

Review 5.  Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis.

Authors:  Stephanie G E Amos; Marion Garreau; Luca Buzzetti; Jerome Waser
Journal:  Beilstein J Org Chem       Date:  2020-05-29       Impact factor: 2.883

6.  DABCO-promoted photocatalytic C-H functionalization of aldehydes.

Authors:  Bruno Maia da Silva Santos; Mariana Dos Santos Dupim; Cauê Paula de Souza; Thiago Messias Cardozo; Fernanda Gadini Finelli
Journal:  Beilstein J Org Chem       Date:  2021-12-21       Impact factor: 2.883

7.  Nickel-catalyzed migratory alkyl-alkyl cross-coupling reaction.

Authors:  Yangyang Li; Yuqiang Li; Long Peng; Dong Wu; Lei Zhu; Guoyin Yin
Journal:  Chem Sci       Date:  2020-09-09       Impact factor: 9.825

Review 8.  Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.

Authors:  Luca Capaldo; Davide Ravelli; Maurizio Fagnoni
Journal:  Chem Rev       Date:  2021-08-06       Impact factor: 60.622

  8 in total

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