Literature DB >> 31990096

Long-Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin-Calixarene Assemblies.

Massimiliano Gaeta1, Giuseppe Sortino1, Rosalba Randazzo1, Ilenia Pisagatti2, Anna Notti2, Maria Elena Fragalà1, Melchiorre F Parisi2, Alessandro D'Urso1, Roberto Purrello1.   

Abstract

The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  calixarenes; chirality induction; circular dichroism; noncovalent interactions; porphyrinoids

Year:  2020        PMID： 31990096     DOI： 10.1002/chem.202000126

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  4 in total

1.  Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System.

Authors:  Penghui Zhang; Yiran Liu; Xinkuo Fang; Li Ma; Yuanyuan Wang; Lukang Ji
Journal:  Gels       Date:  2022-04-26

2.  Self-Assembly of Discrete Porphyrin/Calix[4]tube Complexes Promoted by Potassium Ion Encapsulation.

Authors:  Massimiliano Gaeta; Elisabetta Rodolico; Maria E Fragalà; Andrea Pappalardo; Ilenia Pisagatti; Giuseppe Gattuso; Anna Notti; Melchiorre F Parisi; Roberto Purrello; Alessandro D'Urso
Journal:  Molecules       Date:  2021-01-29       Impact factor: 4.411

3.  Amplification of weak chiral inductions for excellent control over the helical orientation of discrete topologically chiral (M3L2) n polyhedra.

Authors:  Yuya Domoto; Kidai Yamamoto; Shumpei Horie; Zhengsu Yu; Makoto Fujita
Journal:  Chem Sci       Date:  2022-03-22       Impact factor: 9.825

4.  The Impact of Solvent and the Receptor Structure on Chiral Recognition Using Model Acyclic Bisamides Decorated with Glucosamine Pendant Arms.

Authors:  Sylwia Wasiłek; Janusz Jurczak
Journal:  J Org Chem       Date:  2020-08-28       Impact factor: 4.354
  4 in total

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