| Literature DB >> 31970378 |
Nikolay V Kireev1, Oleg A Filippov, Ekaterina S Gulyaeva, Elena S Shubina, Laure Vendier, Yves Canac, Jean-Baptiste Sortais, Noël Lugan, Dmitry A Valyaev.
Abstract
Deprotonation of fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3Br] (R = H, Me, Ph) produces the corresponding diphosphinomethanide derivatives fac-[(κ3P,C,P-Ph2PC(R)PPh2)Mn(CO)3], which are prone to activate H2 to form the hydride complexes fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3H]. The substitution of the dppm bridge improves dramatically the reaction efficiency and this was rationalized by DFT calculations.Entities:
Year: 2020 PMID： 31970378 DOI： 10.1039/c9cc07713h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222