Literature DB >> 31970374

Tracing and elucidating visible-light mediated oxidation and C-H functionalization of amines using mass spectrometry.

Wanpeng Ai1, Yunpeng Gao1, Jinjuan Xue1, Xiaoyun Liu2, Huwei Liu1, Jianbo Wang1, Yu Bai1.   

Abstract

The co-existing mechanism of visible light mediated direct oxidation and C-H functionalization of amines was investigated by capturing all the intermediates using online mass spectrometry. The two-step dehydrogenation of amine involving a proton coupled electron transfer (PCET) process was revealed for the first time.

Entities:  

Year:  2020        PMID: 31970374     DOI: 10.1039/c9cc09629a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Electrocatalytic redox neutral [3 + 2] annulation of N-cyclopropylanilines and alkenes.

Authors:  Qi Wang; Qile Wang; Yuexiang Zhang; Yasmine M Mohamed; Carlos Pacheco; Nan Zheng; Richard N Zare; Hao Chen
Journal:  Chem Sci       Date:  2020-11-09       Impact factor: 9.825

  1 in total

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