| Literature DB >> 31964087 |
Ryota Terao1, Takashi Nakazono1,2, Alexander Rene Parent2,3, Ken Sakai1,2,4.
Abstract
Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O-O bond formation.Entities:
Keywords: copper; homogeneous catalysis; photocatalysis; water splitting
Year: 2016 PMID： 31964087 DOI： 10.1002/cplu.201600263
Source DB: PubMed Journal: Chempluschem ISSN： 2192-6506 Impact factor: 2.863